Polarization transfer via long range couplingas a simple one-dimensional NMR technique for 1H-13C correlation. Application to the definitive assignment of the syn and anti 13C δ resonances of 2-substituted adamantanes
作者： Ashraf N. Abdel-Sayed , Ludwig Bauer
DOI: 10.1016/S0040-4039(86)80033-8
关键词: Stereochemistry 、 Carbon-13 NMR 、 Spectral line 、 Nuclear magnetic resonance spectroscopy 、 Polarization (waves) 、 Chemistry 、 Crystallography
摘要: Abstract The syn and anti δ resonances in 13C NMR spectra of 2-substituted adamantanes wereassigned unequivocally by means selective polarization transfer from γ- protons via 2-bond carbon-proton coupling.
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