Evidence for the intermediacy of discrete classical carbanions in the rearrangements of the 5-norbornenyl and benzonorbornenyl systems

作者： Michael N. Paddon-Row , Douglas N. Butler , Ronald N. Warrener

关键词: Chemistry 、 Carbanion 、 Organic chemistry 、 Computational chemistry 、 Product (mathematics) 、 Norbornadiene 、 Labelling 、 Birch reduction 、 Molecular medicine

摘要: The carbanions in the title series were generated via Birch reduction of norbornadiene and benzonorbornadiene on basis both product labelling studies evidence is presented which favours intermediacy classical carbanions.

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Evidence for the intermediacy of discrete classical carbanions in the rearrangements of the 5-norbornenyl and benzonorbornenyl systems

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Evidence for the intermediacy of discrete classical carbanions in the rearrangements of the 5-norbornenyl and benzonorbornenyl systems

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