The heat of adsorption of Van der Waals gases on metallic substrates: A special example of metal-non-metal adhesion
作者： A.R. Miedema , B.E. Nieuwenhuys
DOI: 10.1016/0039-6028(81)90074-1
关键词: Chemistry 、 Physical chemistry 、 Thermodynamics 、 Van der Waals radius 、 Metal 、 Noble gas 、 van der Waals force 、 Molecule 、 Van der Waals strain 、 Adhesion 、 Adsorption
摘要: Abstract The heat of adsorption noble gas molecules A on metallic substrates B is described in terms the energy adhesion, generated at interface shared by adsorbed and substrate. adhesion (and hence adsorption) related to zero temperature surface energies γ0 two materials Δγ a d = −2Φ(γ 0 Aγ B) 1 2 . relation presented from which approximate constant Φ can be derived for arbitrary combinations metals Van der Waals crystals. Predictions gases are tabular form.
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