Ultra-violet Absorption Spectra of the Diazines

作者: K. KEITH INNES , JAMES A. MERRITT , WAYNE C. TINCHER , SHELBY G. TILFORD

DOI: 10.1038/187500A0

关键词: PyrazineMoleculeMolecular electronic transitionPyridazineX-ray absorption fine structurePyrimidineAbsorption spectroscopyMaterials scienceAnalytical chemistryAbsorption (chemistry)

摘要: NO rotational analysis of an electronic transition has been reported for a molecule containing as many ten atoms. However, preliminary spectrograms pyrazine (Fig. 1) showed fine structure clearly susceptible to 2). Twelve bands which were relatively free from overlapping photographed in the fourth order 150,000-line grating, and constants accurate band centres obtained. Similar treatment was possible 3200 A. absorption pyrimidine 3700 by pyridazine. The obtained respective 0–0 are :

参考文章(4)
R.C. Hirt, Ultraviolet absorption vapor spectra of pyrazine and chloropyrazine Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 12, pp. 114- 126 ,(1958) , 10.1016/0371-1951(58)80024-7
Fred M. Uber, An Experimental Study of the Ultraviolet Absorption Spectrum of Pyrimidine Journal of Chemical Physics. ,vol. 9, pp. 777- 779 ,(1941) , 10.1063/1.1750841
R.C. Lord, A.L. Marston, Foil A. Miller, Infra-red and Raman spectra ot the diazines Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 9, pp. 113- 125 ,(1957) , 10.1016/0371-1951(57)80205-7
M. Ito, R. Shimada, T. Kuraishi, W. Mizushima, Ultraviolet Absorption of Pyrazine Vapor Due ton— π Transition The Journal of Chemical Physics. ,vol. 26, pp. 1508- 1515 ,(1957) , 10.1063/1.1743570