Ordering of interstitial nitrogen and oxygen in vanadium near to V8N and V8O
作者： M. Cambini
DOI: 10.1016/0025-5408(74)90093-2
关键词: Vanadium 、 Oxygen 、 Chemistry 、 Triclinic crystal system 、 Octahedron 、 Suboxide 、 Lattice (order) 、 Electron microscope 、 Crystallography 、 Electron diffraction 、 Mechanical engineering 、 General Materials Science 、 Mechanics of Materials 、 Condensed matter physics
摘要: The ordered structure of the V8N subnitride was studied by X-rays, electron diffraction and microscopy. exists in two different modifications (α′ α″). vanadium sublattice both phases is pseudo-tetragonal, reality triclinic, with lattice parameters: αo = bo 3.114 A, co 2.994 βo 90.5o ± 0.1o, γo 90o. proposed unit cell α′-V8N has dimensions: a 2√2 ao, c 2co corresponds to V32N4. Doublets nitrogen atoms occupy sets octahedral cavities whose shortest axes are aligned along x y directions an fashion. α″-V8N phase periodically twinned modification α′-V8N, twin plane being (001) type. V8O suboxide same as α″-V8N, parameters being: ao 3.11 90.3o
elsevier.com
sci-hub.se 参考文章(18)
D.I Potter, The structure, morphology and orientation relationship of V3N in α-vanadium Journal of the Less Common Metals. ,vol. 31, pp. 299- 309 ,(1973) , 10.1016/0022-5088(73)90165-3
G. Hörz, Solid solubility limit of nitrogen in vanadium at temperatures between 500 and 1500 °C. Precipitation phenomena in the system vanadium-nitrogen Journal of the Less Common Metals. ,vol. 35, pp. 207- 225 ,(1974) , 10.1016/0022-5088(74)90232-X
M. Cambini, On the structural and morphological relationships between the VOx and β-vanadium suboxides in the two-phase system Materials Research Bulletin. ,vol. 5, pp. 287- 300 ,(1970) , 10.1016/0025-5408(70)90013-9
Howard Epstein, Barry Goldstein, Donald Potter, Metastable phases in dilute alloys of vanadium with nitrogen Scripta Metallurgica. ,vol. 7, pp. 717- 719 ,(1973) , 10.1016/0036-9748(73)90120-8
M. Cambini, G. Pellegrini, S. Amelinckx, Substructure of γ-vanadium suboxide resulting from long range ordering of oxygen Materials Research Bulletin. ,vol. 6, pp. 791- 803 ,(1971) , 10.1016/0025-5408(71)90116-4
D Gunwaldsen, D Potter, A long period superlattice in dilute vanadium-oxygen alloys Journal of the Less Common Metals. ,vol. 34, pp. 97- 106 ,(1974) , 10.1016/0022-5088(74)90218-5
J.L. Henry, S.A. O'Hare, R.A. McCune, Marion P. Krug, The vanadium-oxygen system: Phase relations in the vanadium-rich region below 1200 °C Journal of the Less Common Metals. ,vol. 21, pp. 115- 135 ,(1970) , 10.1016/0022-5088(70)90110-4
D.I. Potter, C. Altstetter, PHASE TRANSFORMATIONS IN CONCENTRATED V--N SOLUTIONS. Acta Metallurgica. ,vol. 20, pp. 313- 318 ,(1972) , 10.1016/0001-6160(72)90023-5
G. Brauer, W.-D. Schnell, Zur kenntnis des Systems Vanadium-Stickstoff und des reinen vanadiums Journal of The Less Common Metals. ,vol. 6, pp. 326- 332 ,(1964) , 10.1016/0022-5088(64)90130-4
M. Cambini, R. Serneels, R. Gevers, Ordering of hydrogen in β‐vanadium hydride near to V2H Physica Status Solidi (a). ,vol. 21, ,(1974) , 10.1002/PSSA.2210210245