The Phase System Fe-Ir-S at 1100, 1000 and 800°C

作者: E. Makovicky

DOI: 10.1180/MINMAG.1999.063.3.09

关键词: Analytical chemistryStereochemistrySolubilityField (physics)ChemistryPhase (matter)Geochemistry and Petrology

摘要: Phase relations in the dry condensed Fe-Ir-S system were determined at 1100, 1000 and 800 degrees C. Orientational runs performed 500 Between 1100 C, comprises five sulphides an uninterrupted field of gamma (Fe,Ir). Fe (sub 1-x) S dissolves 5.8 at.% Ir 3.4 C 1.0 The solubility 2 3 , IrS approximately 3) increases with decreasing temperature, reaching 2.5 latter two Thiospinel "FeIr 4 " is non-stoichiometric, from 22.3) 19.8) 58.0) to 18.9) 23.1) depending on a s i.e. phase association. absent

参考文章(10)
S. Murphy, S. A. Toma, The composition and properties of some native platinum concentrates from different localities Canadian Mineralogist. ,vol. 15, pp. 59- 69 ,(1977)
E. Slansky, L. M. Barron, D. Suppel, Z. Johan, M. Ohnenstetter, Platinum mineralization in the Alaskan-type intrusive complexes near Fifield, N.S.W., Australia. Part 2. Platinum-group minerals in placer deposits at Fifield Mineralogy and Petrology. ,vol. 43, pp. 161- 180 ,(1991) , 10.1007/BF01166889
Ortrud Kubaschewski, Iron-binary phase diagrams ,(1982)
Lothar Wöhler, K. Ewald, H. G. Krall, Die Sulfide, Selenide und Telluride der sechs Platinmetalle Berichte der deutschen chemischen Gesellschaft (A and B Series). ,vol. 66, pp. 1638- 1652 ,(1933) , 10.1002/CBER.19330661106
S. Jobic, P. Deniard, R. Brec, J. Rouxel, M.G.B. Drew, W.I.F. David, Properties of the transition metal dichalcogenides: The case of IrS2 and IrSe2 Journal of Solid State Chemistry. ,vol. 89, pp. 315- 327 ,(1990) , 10.1016/0022-4596(90)90273-Z
L. J. Swartzendruber, The Fe−Ir (Iron-Iridium) system Bulletin of Alloy Phase Diagrams. ,vol. 5, pp. 134- 134 ,(1984) , 10.1007/BF02868944
Olivier Legendre, Thierry Auge, Pt-Fe nuggets from alluvial deposits in eastern Madagascar Canadian Mineralogist. ,vol. 30, pp. 983- 1004 ,(1992)
Donald C. Harris, Thorolf W. Weiser, Louis J. Cabri, Mineralogy and Distribution of Platinum-group Mineral (PGM) Placer Deposits of the World Exploration and Mining Geology. ,vol. 2, pp. 73- 167 ,(1996)