Instrumented impact property and fracture process behavior of composite rubber toughened abs terpolymer

作者: Zhisheng Yu , Chaoxian Wang , Yang Li , Yurong Wang

DOI: 10.1002/APP.38360

关键词: Composite materialNatural rubberFractographyPolybutadieneFracture (geology)CavitationFracture mechanicsComposite numberCopolymerMaterials science

摘要: A series of low-cis-1,4/high-cis-1,4 polybutadiene composite rubber toughened poly(acrylonitrile-butadiene-styrene) (ABS) terpolymers were prepared and characterized. The morphological analysis shows that specimens exhibit common characteristics two single rubbers while mechanical measurements reveal better comprehensive properties can be obtained as more Ni-9004 blended in rubber. When increasing Ni-9004/Li-700A ratio, one brittle–ductile transition occurs at 5.0 wt % usage three regions exist under 10.0 usage. In addition, the characteristic force–time curves fractography demonstrate failure behavior crack propagation mode effectively evaluated. Conclusively, quasi-brittle fracture seen for with obvious cavitation matrix stripping followed by riverlike fibrous periodical Wallner stripes, whereas ductile is observed those alternate parabolic firework patterns accompanying stress-whitening ligament-forming progress. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

参考文章(25)
A van der Wal, J.J Mulder, H.A Thijs, R.J Gaymans, Fracture of polypropylene: 1. The effect of molecular weight and temperature at low and high test speed Polymer. ,vol. 39, pp. 5467- 5475 ,(1998) , 10.1016/S0032-3861(97)10278-6
A van der Wal, J.J Mulder, R.J Gaymans, Fracture of polypropylene : 2. The effect of crystallinity Polymer. ,vol. 39, pp. 5477- 5481 ,(1998) , 10.1016/S0032-3861(97)10279-8
C.M Tai, Robert K.Y Li, C.N Ng, Impact behaviour of polypropylene/polyethylene blends Polymer Testing. ,vol. 19, pp. 143- 154 ,(2000) , 10.1016/S0142-9418(98)00080-4
S. Jose, S. Thomas, E. Lievana, J. Karger-Kocsis, Morphology and mechanical properties of polyamide 12 blends with styrene/ethylene–butylene/styrene rubbers with and without maleation Journal of Applied Polymer Science. ,vol. 95, pp. 1376- 1387 ,(2005) , 10.1002/APP.21362
Zhisheng Yu, Yang Li, Zhongfu Zhao, Chaoxian Wang, Juan Yang, Chunqing Zhang, Zhansheng Li, Yurong Wang, Effect of rubber types on synthesis, morphology, and properties of ABS resins Polymer Engineering and Science. ,vol. 49, pp. 2249- 2256 ,(2009) , 10.1002/PEN.21475
C. B. Bucknall, A. Karpodinis, X. C. Zhang, A model for particle cavitation in rubber-toughened plastics Journal of Materials Science. ,vol. 29, pp. 3377- 3383 ,(1994) , 10.1007/BF00352036
Y. Duan, A. Saigal, R. Greif, M. A. Zimmerman, Impact behavior and modeling of engineering polymers Polymer Engineering and Science. ,vol. 43, pp. 112- 124 ,(2003) , 10.1002/PEN.10010