EFEITO DE MOLÉCULAS AUTO-ORGANIZÁVEIS NA RESISTÊNCIA À CORROSÃO DA LIGA AA2024-T3

作者: Solange de Souza , Daniel Sierra Yoshikawa , Sérgio Luiz de Assis , Wagner Izaltino Alves dos Santos , Isolda Costa

DOI: 10.4322/TMM.00603002

关键词: Materials scienceAluminiumDielectric spectroscopyChemical engineeringChromate conversion coatingAlloyCorrosionAluminium alloyPassivationMetallurgyChromium

摘要: Coatings based on self-assembling molecules (SAM) have been studied as possible substitutes to the chromate conversion coatings for corrosion protection of aluminium alloys. In this work, influence alkane diphosphonates resistance AA2024-T3 alloy is investigated. The investigation carried out by electrochemical impedance spectroscopy, potentiodynamic polarization techniques, accelerated experiments and scanning electron microscopy technique. Results show that surface treatment with decreased due corrosive attack SAM solution surface. used passivation chromium (VI) also caused surface, leading slight decreases in resistance. produced best associated growth sealing oxide.

参考文章(11)
Kevin R. Stewart, George M. Whitesides, Herman P. Godfried, Isaac F. Silvera, Improved adhesion of thin conformal organic films to metal surfaces Review of Scientific Instruments. ,vol. 57, pp. 1381- 1383 ,(1986) , 10.1063/1.1138605
Solange de Souza, Smart coating based on polyaniline acrylic blend for corrosion protection of different metals Surface & Coatings Technology. ,vol. 201, pp. 7574- 7581 ,(2007) , 10.1016/J.SURFCOAT.2007.02.027
Iris Maege, Evelin Jaehne, Axel Henke, Hans-Juergen P Adler, Christian Bram, Christian Jung, Martin Stratmann, Self-assembling adhesion promoters for corrosion resistant metal polymer interfaces Progress in Organic Coatings. ,vol. 34, pp. 1- 12 ,(1998) , 10.1016/S0300-9440(98)00010-1
F.M. Reis, H.G. de Melo, I. Costa, EIS investigation on Al 5052 alloy surface preparation for self-assembling monolayer Electrochimica Acta. ,vol. 51, pp. 1780- 1788 ,(2006) , 10.1016/J.ELECTACTA.2005.02.118
S. de Souza, D.S. Yoshikawa, W.A.S. Izaltino, S.L. Assis, I. Costa, Self-assembling molecules as corrosion inhibitors for 1050 aluminum Surface & Coatings Technology. ,vol. 204, pp. 3238- 3242 ,(2010) , 10.1016/J.SURFCOAT.2010.03.021
Luis E.M. Palomino, Idalina V. Aoki, Hercílio G. de Melo, Microstructural and electrochemical characterization of Ce conversion layers formed on Al alloy 2024-T3 covered with Cu-rich smut Electrochimica Acta. ,vol. 51, pp. 5943- 5953 ,(2006) , 10.1016/J.ELECTACTA.2006.03.036
WR Osório, JE Spinelli, IL Ferreira, AJEA Garcia, None, The roles of macrosegregation and of dendritic array spacings on the electrochemical behavior of an Al–4.5 wt.% Cu alloy Electrochimica Acta. ,vol. 52, pp. 3265- 3273 ,(2007) , 10.1016/J.ELECTACTA.2006.10.004
A. Baltat-Bazia, N. Celati, Michel Keddam, Hisasi Takenouti, R. Wiart, Electrochemical Impedance Spectroscopy and Electron Microscopies Applied to the Structure of Anodic Oxide Layers on Pure Aluminium Materials Science Forum. ,vol. 111-112, pp. 359- 368 ,(1992) , 10.4028/WWW.SCIENTIFIC.NET/MSF.111-112.359