Absolute rate constant for the chemiluminescent reaction of atomic oxygen with nitric oxide

作者: Masako Sutoh , Yumio Morioka , Masatoshi Nakamura

DOI: 10.1063/1.438878

关键词: Light emissionOxygenChemiluminescenceWavelengthReaction rate constantSpectral power distributionBrightnessChemistryChemical reactionAnalytical chemistry

摘要: The absolute rate constant for light emission from the NO–O reaction has been determined, as a function of wavelength, by using standard brightness source, which surface uniform brightness. spectral distribution measured between 0.4 and 1.4 μm is in good agreement with those previous studies except little difference near infrared region. influence NO–O3 chemiluminescence demonstrated atomic oxygen production O2 discharges.

参考文章(15)
L. F. Phillips, H. I. Schiff, Mass Spectrometric Studies of Atom Reactions. I. Reactions in the Atomic Nitrogen‐Ozone System The Journal of Chemical Physics. ,vol. 36, pp. 1509- 1517 ,(1962) , 10.1063/1.1732772
H. P. Broida, H. I. Schiff, T. M. Sugden, Observations on the chemiluminescent reaction of nitric oxide with atomic oxygen Transactions of the Faraday Society. ,vol. 57, pp. 259- 265 ,(1961) , 10.1039/TF9615700259
M. VANPEE, K. D. HILL, W. R. KINEYKO, Absolute rate constant measurements for the radiative combination ofatomic oxygen with nitric oxide AIAA Journal. ,vol. 9, pp. 135- 139 ,(1971) , 10.2514/3.6134
G. A. Woolsey, P. H. Lee, W. D. Slafer, Measurement of the rate constant for NO–O chemiluminescence using a calibrated piston source of light Journal of Chemical Physics. ,vol. 67, pp. 1220- 1224 ,(1977) , 10.1063/1.434932
Robert A. Young, Robert L. Sharpless, Chemiluminescent Reactions Involving Atomic Oxygen and Nitrogen The Journal of Chemical Physics. ,vol. 39, pp. 1071- 1102 ,(1963) , 10.1063/1.1734361
Paul Harteck, Robert R. Reeves, Gene Mannella, Reaction of Oxygen Atoms with Nitric Oxide The Journal of Chemical Physics. ,vol. 29, pp. 1333- 1335 ,(1958) , 10.1063/1.1744718
MAA Clyne, Brian Arthur Thrush, Mechanism of chemiluminescent combination reactions involving oxygen atoms Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 269, pp. 404- 418 ,(1962) , 10.1098/RSPA.1962.0185
A. Fontijn, C. B. Meyer, H. I. Schiff, Absolute Quantum Yield Measurements of the NO–O Reaction and Its Use as a Standard for Chemiluminescent Reactions Journal of Chemical Physics. ,vol. 40, pp. 64- 70 ,(1964) , 10.1063/1.1724895
K.H. Becker, W. Groth, D. Thran, The air glow reaction NO + O + (M) → NO*2 + (M) at low pressures Chemical Physics Letters. ,vol. 6, pp. 583- 586 ,(1970) , 10.1016/0009-2614(70)85232-0