Mesoporous metal oxides templated by FDU-12 using a new convenient method
作者： W.B. Yue , W.Z. Zhou
DOI: 10.1016/S0167-2991(07)81056-1
关键词: Crystal growth 、 Non-blocking I/O 、 Molecular sieve 、 Mesoporous silica 、 Mesoporous organosilica 、 Inorganic chemistry 、 Mesoporous material 、 Materials science 、 Transition metal 、 Adsorption
摘要: Abstract A solid-liquid synthetic method has been developed to produce crystalline mesoporous transition metal oxides, Co3O4, NiO, and CeO2, using cage-containing FDU-12 silica as a hard template. Structural characterisation of the products was carried out XRD, HRTEM N2 adsorption/desorption. The formation mechanisms these new materials were investigated. It found that crystal symmetry oxides significant influence on growth inside cage-dominated mesopores.
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sci-hub.se 参考文章(30)
P. Poizot, S. Laruelle, S. Grugeon, L. Dupont, J-M. Tarascon, Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries Nature. ,vol. 407, pp. 496- 499 ,(2000) , 10.1038/35035045
Y. Wang, C.-M. Yang, W. Schmidt, B. Spliethoff, E. Bill, F. Schüth, Weakly ferromagnetic ordered mesoporous Co₃O₄ synthesized by nanocasting from vinyl-functionalized cubic Ia3d mesoporous silica Advanced Materials. ,vol. 17, pp. 53- 56 ,(2005) , 10.1002/ADMA.200400777
Jie Fan, Chengzhong Yu, Jie Lei, Qiang Zhang, Tingcheng Li, Bo Tu, Wuzong Zhou, Dongyuan Zhao, Low-Temperature Strategy to Synthesize Highly Ordered Mesoporous Silicas with Very Large Pores Journal of the American Chemical Society. ,vol. 127, pp. 10794- 10795 ,(2005) , 10.1021/JA052619C
B. Tian, X. Liu, H. Yang, S. Xie, C. Yu, B. Tu, D. Zhao, General Synthesis of Ordered Crystallized Metal Oxide Nanoarrays Replicated by Microwave‐Digested Mesoporous Silica Advanced Materials. ,vol. 15, pp. 1370- 1374 ,(2003) , 10.1002/ADMA.200305211
Weihua Shen, Xiaoping Dong, Yufng Zhu, Hangrong Chen, Jianlin Shi, Mesoporous CeO2 and CuO-loaded mesoporous CeO2: Synthesis, characterization, and CO catalytic oxidation property Microporous and Mesoporous Materials. ,vol. 85, pp. 157- 162 ,(2005) , 10.1016/J.MICROMESO.2005.06.006
Wuzong Zhou, Abdelhamid Sayari, Wenhui Wang, Synthesis of periodic mesoporous phenylenesilica under acidic conditions with novel molecular order in the pore walls Chemistry of Materials. ,vol. 15, pp. 4886- 4889 ,(2003) , 10.1021/CM034809X
Yi Meng Wang, Zheng Ying Wu, Jian Hua Zhu, Surface functionalization of SBA-15 by the solvent-free method Journal of Solid State Chemistry. ,vol. 177, pp. 3815- 3823 ,(2004) , 10.1016/J.JSSC.2004.07.013
Jie Fan, Chengzhong Yu, Feng Gao, Jie Lei, Bozhi Tian, Limin Wang, Qian Luo, Bo Tu, Wuzong Zhou, Dongyuan Zhao, Cubic Mesoporous Silica with Large Controllable Entrance Sizes and Advanced Adsorption Properties Angewandte Chemie International Edition. ,vol. 42, pp. 3146- 3150 ,(2003) , 10.1002/ANIE.200351027
Dongyuan Zhao, Qisheng Huo, Jianglin Feng, Bradley F. Chmelka, Galen D. Stucky, Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures Journal of the American Chemical Society. ,vol. 120, pp. 6024- 6036 ,(1998) , 10.1021/JA974025I
Chun-Shen Cheng, M. Serizawa, H. Sakata, T. Hirayama, Electrical conductivity of Co3O4 films prepared by chemical vapour deposition Materials Chemistry and Physics. ,vol. 53, pp. 225- 230 ,(1998) , 10.1016/S0254-0584(98)00044-3