Mechanochromic Photonic Gels

作者: Edwin P. Chan , Joseph J. Walish , Augustine M. Urbas , Edwin L. Thomas

DOI: 10.1002/ADMA.201300692

关键词: NanoparticleStopbandPhotonic crystalNanotechnologyCopolymerPhotonicsMaterials scienceDeformation (engineering)Light intensityPolymerMechanical engineeringGeneral Materials ScienceMechanics of Materials

摘要: Polymer gels are remarkable materials with physical structures that can adapt significantly and quite rapidly changes in the local environment, such as temperature, light intensity, electrochemistry, mechanical force. An interesting phenomenon observed certain polymer gel systems is mechanochromism - a change color due to deformation. Mechanochromic photonic periodically structured engineered stopband be tuned by forces reflect specific colors. These have potential mechanochromic sensors because both optical properties highly tailorable via incorporation of diluents, solvents, nanoparticles, or polymers, application stimuli pH, electric strain fields. Recent advances display strain-dependent discussed. In particular, this discussion focuses primarily on polymer-based directly indirectly fabricated self-assembly, these promising soft material platforms for scalable sensors.

参考文章(89)
Joshua N. Winn, Robert D. Meade, Steven G. Johnson, John D. Joannopoulos, Photonic Crystals: Molding the Flow of Light ,(1995)
Rudolf Zentel, Gertrude Reckert, Liquid crystalline elastomers based on liquid crystalline side group, main chain and combined polymers Macromolecular Chemistry and Physics. ,vol. 187, pp. 1915- 1926 ,(1986) , 10.1002/MACP.1986.021870811
Chaitanya K. Ullal, Sebastian Primpke, Roman Schmidt, Ulrike Böhm, Alexander Egner, Philipp Vana, Stefan W. Hell, Flexible microdomain specific staining of block copolymers for 3D optical nanoscopy. Macromolecules. ,vol. 44, pp. 7508- 7510 ,(2011) , 10.1021/MA201504F
Andrew Richard Parker, 515 million years of structural colour Journal of Optics. ,vol. 2, ,(2000) , 10.1088/1464-4258/2/6/201
Tomasz Kazmierczak, Hyunmin Song, Anne Hiltner, Eric Baer, Polymeric One-Dimensional Photonic Crystals by Continuous Coextrusion Macromolecular Rapid Communications. ,vol. 28, pp. 2210- 2216 ,(2007) , 10.1002/MARC.200700367
Shandon D Hart, Garry R Maskaly, Burak Temelkuran, Peter H Prideaux, John D Joannopoulos, Yoel Fink, External Reflection from Omnidirectional Dielectric Mirror Fibers Science. ,vol. 296, pp. 510- 513 ,(2002) , 10.1126/SCIENCE.1070050
P. A. Bermel, M. Warner, Photonic band structure of highly deformable self-assembling systems. Physical Review E. ,vol. 65, pp. 010702- ,(2001) , 10.1103/PHYSREVE.65.010702
M. Mitov, E. Nouvet, N. Dessaud, Polymer-stabilized cholesteric liquid crystals as switchable photonic broad bandgaps European Physical Journal E. ,vol. 15, pp. 413- 419 ,(2004) , 10.1140/EPJE/I2004-10058-4
Y.-J. Lee, P.V. Braun, Tunable Inverse Opal Hydrogel pH Sensors Advanced Materials. ,vol. 15, pp. 563- 566 ,(2003) , 10.1002/ADMA.200304588