New Adhesive Materials Based on Silicon-Substituted Polynorbornenes
作者： E. V. Bermesheva , D. A. Alentiev , A. P. Moskalets , M. V. Bermeshev
DOI: 10.1134/S1560090419030011
关键词: Metathesis 、 Silicon 、 Adhesion 、 Materials science 、 Polymer chemistry 、 Silylation 、 Polymer 、 Adhesive 、 Grubbs' catalyst 、 Substituent 、 Materials Chemistry 、 Polymers and Plastics 、 Ceramics and Composites
摘要: Two metathesis homopolymers with tri(n-propoxy)silyl and tri(n-butoxy)silyl side substituents are synthesized, their adhesive properties investigated. High-molecular-weight polymers prepared in the presence of first-generation Grubbs catalyst a good yield. Adhesive studied by probe tack method at different temperatures. Using example polymers, for first time, it is shown that pressure-sensitive adhesives can be obtained on basis polynorbornenes. The effect length silicon substituent work adhesion evaluated.
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