Antibacterial behavior of halloysite nanotubes decorated with copper nanoparticles in a novel mixed matrix membrane for water purification

作者: Linlin Duan , Qianqian Zhao , Jindun Liu , Yatao Zhang

DOI: 10.1039/C5EW00140D

关键词: UltrafiltrationComposite materialMembraneChemical engineeringCopperPhase inversion (chemistry)HalloysiteMaterials scienceContact angleNanoparticleAtom-transfer radical-polymerization

摘要: Poly(4-vinylpyridine) (P4VP) with various molecular weights was grafted onto halloysite nanotubes (HNTs) via reverse atom transfer radical polymerization (RATRP). Then copper nanoparticles (Cu NPs) were loaded the surface of HNTs by complexation and reduction NPs@HNTs). Finally, a novel mixed matrix membrane, polyethersulfone (PES) ultrafiltration containing Cu NPs@HNTs fabricated classical phase inversion method. The results showed that pure water flux hybrid membrane greatly enhanced, maximum could reach as high 212 L m−2 h−1. contact angle atomic force microscopy (AFM) indicated hydrophilicity prepared membranes improved became smoother, compared virgin membranes. Importantly, antibacterial test good activity against E. coli bacteriostasis rate 94.5%.

参考文章(31)
Chaoying Wan, Ming Li, Xin Bai, Yong Zhang, Synthesis and Characterization of Photoluminescent Eu(III) Coordination Halloysite Nanotube-Based Nanohybrids Journal of Physical Chemistry C. ,vol. 113, pp. 16238- 16246 ,(2009) , 10.1021/JP9051648
Ming-Liang Luo, Jian-Qing Zhao, Wu Tang, Chun-Sheng Pu, Hydrophilic modification of poly(ether sulfone) ultrafiltration membrane surface by self-assembly of TiO2 nanoparticles Applied Surface Science. ,vol. 249, pp. 76- 84 ,(2005) , 10.1016/J.APSUSC.2004.11.054
Yuri M. Lvov, Dmitry G. Shchukin, Helmuth Möhwald, Ronald R. Price, Halloysite Clay Nanotubes for Controlled Release of Protective Agents ACS Nano. ,vol. 2, pp. 814- 820 ,(2008) , 10.1021/NN800259Q
Vahid Vatanpour, Sayed Siavash Madaeni, Laleh Rajabi, Sirus Zinadini, Ali Ashraf Derakhshan, None, Boehmite nanoparticles as a new nanofiller for preparation of antifouling mixed matrix membranes Journal of Membrane Science. ,vol. 401-402, pp. 132- 143 ,(2012) , 10.1016/J.MEMSCI.2012.01.040
Colin M. Hessel, Varun P. Pattani, Michael Rasch, Matthew G. Panthani, Bonil Koo, James W. Tunnell, Brian A. Korgel, Copper selenide nanocrystals for photothermal therapy. Nano Letters. ,vol. 11, pp. 2560- 2566 ,(2011) , 10.1021/NL201400Z
Sirus Zinadini, Ali Akbar Zinatizadeh, Masoud Rahimi, Vahid Vatanpour, Hadis Zangeneh, Preparation of a novel antifouling mixed matrix PES membrane by embedding graphene oxide nanoplates Journal of Membrane Science. ,vol. 453, pp. 292- 301 ,(2014) , 10.1016/J.MEMSCI.2013.10.070
Yuri Lvov, Elshad Abdullayev, Functional polymer–clay nanotube composites with sustained release of chemical agents Progress in Polymer Science. ,vol. 38, pp. 1690- 1719 ,(2013) , 10.1016/J.PROGPOLYMSCI.2013.05.009
Jingyi Zhang, Yatao Zhang, Yifeng Chen, Lei Du, Bing Zhang, Haoqin Zhang, Jindun Liu, Kaijuan Wang, Preparation and Characterization of Novel Polyethersulfone Hybrid Ultrafiltration Membranes Bending with Modified Halloysite Nanotubes Loaded with Silver Nanoparticles Industrial & Engineering Chemistry Research. ,vol. 51, pp. 3081- 3090 ,(2012) , 10.1021/IE202473U
Chuochuo Liu, Liang Yu, Yatao Zhang, Bing Zhang, Jindun Liu, Haoqin Zhang, Preparation of poly(sodium acrylate-acrylamide) superabsorbent nanocomposites incorporating graphene oxide and halloysite nanotubes RSC Advances. ,vol. 3, pp. 13756- 13763 ,(2013) , 10.1039/C3RA23094E