Process intensification in hydrogen production from coal and biomass via the use of membrane-based reactive separations
作者： Paul KT Liu , Muhammad Sahimi , Theodore T Tsotsis
DOI: 10.1016/J.COCHE.2012.06.001
关键词: Hydrogen 、 Pyrolysis 、 Syngas 、 Organic chemistry 、 Water-gas shift reaction 、 Coal 、 Biomass 、 Chemical engineering 、 Membrane 、 Hydrogen production 、 Chemistry
摘要: We summarize here our recent efforts in hydrogen production from coal and biomass using membrane-based reactive separations. utilize two different types of membranes, namely supported carbon molecular sieve (CMS) which are made via the pyrolysis polymeric precursors Pd Pd-alloy membranes prepared electroless plating techniques. discuss development ‘one-box’ process to economically produce pure coal-derived biomass-derived syngas presence its common impurities through use water gas shift reaction CMS an impurity-tolerant commercial Co/Mo/Al2O3 catalyst. conclude by discussing during ultra-pure biomass.
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