Sorption and catalysis by robust microporous metalloporphyrin framework solids
作者： Dennis W. Smithenry , Scott R. Wilson , Shirley Nakagaki , Kenneth S. Suslick
DOI: 10.1142/S1088424617500791
关键词: Sorption 、 Porphyrin 、 Nanoporous 、 Isostructural 、 Crystallography 、 Catalysis 、 Microporous material 、 Manganese 、 Chemistry 、 Metal
摘要: Two isostructural metalloporphyrin framework solids have been synthesized. Both frameworks contains manganese(III) metal complexes of trans-dicarboxylateporphyrins whose peripheralcarboxylates coordinate the edges tetrahedral Zn4O+6 clusters; two metalloporphyrins explored are Mn(III) and Co(II). The cubic interpenetrated 72% free volume 4 × 7 A averaged size pores. evacuated robust retain a structure open to sorption substrates with medium polarity. manganese porphyrin catalyzes hydroxylation cyclic linear alkanes iodosylbenzene as oxidant in size- polarity-selective manner. In addition, catalysis was found occur within pores, making this rare case solid interior catalysis.
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