Chiral recognition of odorants (+)- and (-)-carvone by phospholipid monolayers
作者： Suram Pathirana , William C. Neely , Lawrence J. Myers , Vitaly Vodyanoy
DOI: 10.1021/JA00030A041
关键词: Chemistry 、 Stereochemistry 、 Phospholipid 、 Atmospheric temperature range 、 Carvone 、 Crystallography 、 Surface pressure 、 Phosphatidylcholine 、 Monolayer
摘要: Interactions of the odorants (+)- and (-)-carvone with L-α-1,2-dipalmitoyl-sn-glycero-3-phosphocholine (L-DPPC) monolayers were studied using surface pressure potential versus area isotherms measured in temperature range 10-35 o C presence absence 5 mM subphase. The data indicate that L-DPPC absorb twice as much heat those (+)-carvone when compressed at 30 C. Under same conditions, undergo a larger entropy change than
acs.org
sci-hub.se 参考文章(0)