MECHANISMS OF THE GAS-PHASE REACTIONS OF AROMATIC HYDROCARBONS AND PAHS WITH OH AND NO 3 RADICALS
作者： Roger Atkinson , Janet Arey
DOI: 10.1080/10406630601134243
关键词: Benzene 、 Chemistry 、 Alkylbenzenes 、 Naphthalene 、 Reaction rate constant 、 Photochemistry 、 Radical 、 Hydroxyl radical 、 Kinetics 、 Reaction mechanism
摘要: Chemical removal for the simple monocyclic aromatic hydrocarbons (benzene and C 1 -C 3 alkylbenzenes) naphthalene 2 alkylnaphthalenes in atmosphere is by reaction with hydroxyl (OH) radicals. Naphthalene may also be removed, but to a much lesser extent, nitrate (NO ) While rate constants gas-phase reactions of OH radicals NO many have been measured, detailed mechanisms these radical-and radical-initiated are less well understood, especially alkylnaphthalenes. Here we present available data on occurring under laboratory conditions attempt reconcile ambient atmospheric measurements. The radical benzene alkylbenzenes ...
sci-hub.se 参考文章(57)
K. Lorenz, R. Zellner, Kinetics of the Reactions of OH-Radicals with Benzene, Benzene-d6 and Naphthalene Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 87, pp. 629- 636 ,(1983) , 10.1002/BBPC.19830870805
Nigel J. Bunce, Lina Liu, Jiang Zhu, Douglas A. Lane, Reaction of naphthalene and its derivatives with hydroxyl radicals in the gas phase Environmental Science & Technology. ,vol. 31, pp. 2252- 2259 ,(1997) , 10.1021/ES960813G
Janet Arey, Roger Atkinson, Barbara Zielinska, Patricia A. McElroy, Diurnal concentrations of volatile polycyclic aromatic hydrocarbons and nitroarenes during a photochemical air pollution episode in glendora California Environmental Science & Technology. ,vol. 23, pp. 321- 327 ,(1989) , 10.1021/ES00180A009
C. Bloss, V. Wagner, M. E. Jenkin, R. Volkamer, W. J. Bloss, J. D. Lee, D. E. Heard, K. Wirtz, M. Martin-Reviejo, G. Rea, J. C. Wenger, M. J. Pilling, Development of a detailed chemical mechanism (MCMv3.1) for the atmospheric oxidation of aromatic hydrocarbons Atmospheric Chemistry and Physics. ,vol. 5, pp. 641- 664 ,(2004) , 10.5194/ACP-5-641-2005
David Johnson, Severine Raoult, Marie-Thérèse Rayez, Jean-Claude Rayez, Robert Lesclaux, An experimental and theoretical investigation of the gas-phase benzene–OH radical adduct + O2 reaction Physical Chemistry Chemical Physics. ,vol. 4, pp. 4678- 4686 ,(2002) , 10.1039/B204415C
Janet Arey, Barbara Zielinska, Roger Atkinson, Arthur M. Winer, Polycyclic aromatic hydrocarbon and nitroarene concentrations in ambient air during a wintertime high-NOx episode in the Los Angeles basin Atmospheric Environment (1967). ,vol. 21, pp. 1437- 1444 ,(1967) , 10.1016/0004-6981(67)90091-1
Davide Vione, Valter Maurino, Claudio Minero, Mirco Lucchiari, Ezio Pelizzetti, Nitration and hydroxylation of benzene in the presence of nitrite/nitrous acid in aqueous solution. Chemosphere. ,vol. 56, pp. 1049- 1059 ,(2004) , 10.1016/J.CHEMOSPHERE.2004.05.027
Barbara Zielinska, John Sagebiel, Jacob D. McDonald, Kevin Whitney, Douglas R. Lawson, Emission rates and comparative chemical composition from selected in-use diesel and gasoline-fueled vehicles. Journal of The Air & Waste Management Association. ,vol. 54, pp. 1138- 1150 ,(2004) , 10.1080/10473289.2004.10470973
Patricia T. Phousongphouang, Janet Arey, Rate Constants for the Gas-Phase Reactions of a Series of Alkylnaphthalenes with the Nitrate Radical Environmental Science & Technology. ,vol. 36, pp. 1947- 1952 ,(2002) , 10.1021/ES026015+
Patricia T. Phousongphouang, Janet Arey, Rate constants for the photolysis of the nitronaphthalenes and methylnitronaphthalenes Journal of Photochemistry and Photobiology A-chemistry. ,vol. 157, pp. 301- 309 ,(2003) , 10.1016/S1010-6030(03)00072-8