Morphological modeling of polymer solidification

作者: Tao Huang , M. R. Kamal

DOI: 10.1002/PEN.11311

关键词: Materials scienceNucleationLamellar structureField (physics)MechanicsMineralogyEvolution equationPolymerElastic energyStrain energyCrystal morphology

摘要: A physical model of semicrystalline polymer solidification is proposed, along with an outline general theoretical aspects morphological modeling. Computational modeling, based on the proposed envelop evolution equation associated a primary nucleation and elastic energy lamellae director field, predicts nucleation-growth processes, domain patterns internal organization spherulitic structures in solidification. Results computer simulation are reported compared experimental observations.

参考文章(55)
John D. Hoffman, G. Thomas Davis, John I. Lauritzen, The Rate of Crystallization of Linear Polymers with Chain Folding Treatise on Solid State Chemistry. pp. 497- 614 ,(1976) , 10.1007/978-1-4684-2664-9_7
J. M. Haudin, N. Billon, Solidification of semi-crystalline polymers during melt processing Steinkopff. pp. 132- 137 ,(1992) , 10.1007/BFB0115588
G. Eder, H. Janeschitz-Kriegl, S. Liedauer, Influence of flow on the crystallization kinetics of polymers Steinkopff. pp. 129- 131 ,(1992) , 10.1007/BFB0115587
Walter Joseph Meyer, Geometry and Its Applications ,(2006)
Hans Gerhard Zachmann, Das Kristallisations- und Schmelzverhalten hochpolymerer Stoffe Fortschritte Der Hochpolymeren-Forschung. ,vol. 3, pp. 581- 687 ,(1964) , 10.1007/BFB0050473
Gert R Strobl, Gert R Strobl, The Physics of Polymers ,(2009)
C. J. G. Plummer, H. -H. Kausch, Real-time image analysis and numerical simulation of isothermal spherulite nucleation and growth in polyoxymethylene Colloid and Polymer Science. ,vol. 273, pp. 719- 732 ,(1995) , 10.1007/BF00658750
Ewa Piorkowska, NONISOTHERMAL CRYSTALLIZATION OF POLYMERS. III: THE MATHEMATICAL DESCRIPTION OF THE FINAL SPHERULITIC PATTERN The Journal of Physical Chemistry. ,vol. 99, pp. 14024- 14031 ,(1995) , 10.1021/J100038A038