Highly conductive paper fabricated with multiwalled carbon nanotubes and poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) by unidirectional drying

作者: Lianghui Huang , Kefu Chen , Chunqing Peng , Rosario A. Gerhardt

DOI: 10.1007/S10853-011-5617-2

关键词: Substrate (chemistry)ConductivityChemical bondComposite materialPEDOT:PSSPulmonary surfactantCeramicPoly(3,4-ethylenedioxythiophene)Fourier transform infrared spectroscopyMaterials science

摘要: Poly(3, 4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) was used to directly disperse multiwalled carbon nanotubes (MWNTs) into a stable solution without the aid of any other surfactants. The coated onto paper substrates and subsequently dried via two different methods: conventional multidirectional drying special unidirectional method with ceramic heating board. samples that were using had lower resistance than when method, which allowed it have better conductivity. For solutions containing 1–4 mg/mL MWNTs, dispersed 1 PEDOT:PSS, measured conductivity ranged from 21 ± 0.5 46 10 S/cm. These values are one three orders magnitude higher those obtained for MWNT films often reported in literature as well we fabricated MWNTs SDBS, or PEDOT:PSS by itself. AFM SEM images showed surface made surfactant very smooth layers tended be thinner It demonstrated FTIR analysis become part 3D structure substrate material because chemical bonding between fibers occurred during stage.

参考文章(28)
Lin-Ren Tsai, Yun Chen, Hyperbranched and thermally cross-linkable oligomer from a new 2,5,7-tri-functional fluorene monomer Journal of Polymer Science Part A. ,vol. 46, pp. 70- 84 ,(2008) , 10.1002/POLA.22359
Rui Yang, Guoping Li, Kunhua Wang, Characterization of structure of comblike polymer by pyrolysis gas chromatography and Fourier transform infrared spectroscopy Journal of Applied Polymer Science. ,vol. 81, pp. 359- 363 ,(2001) , 10.1002/APP.1446
Masanori Imai, Kousuke Akiyama, Tomo Tanaka, Eiichi Sano, Highly strong and conductive carbon nanotube/cellulose composite paper Composites Science and Technology. ,vol. 70, pp. 1564- 1570 ,(2010) , 10.1016/J.COMPSCITECH.2010.05.023
L. Hu, J. W. Choi, Y. Yang, S. Jeong, F. La Mantia, L.-F. Cui, Y. Cui, Highly conductive paper for energy-storage devices Proceedings of the National Academy of Sciences of the United States of America. ,vol. 106, pp. 21490- 21494 ,(2009) , 10.1073/PNAS.0908858106
Y. Chen, K.S. Kang, K.J. Han, K.H. Yoo, Jaehwan Kim, Enhanced optical and electrical properties of PEDOT: PSS films by the addition of MWCNT-sorbitol Synthetic Metals. ,vol. 159, pp. 1701- 1704 ,(2009) , 10.1016/J.SYNTHMET.2009.05.009
L.-F. Liao, C.-F. Lien, D.-L. Shieh, M.-T. Chen, J.-L. Lin, FTIR Study of Adsorption and Photoassisted Oxygen Isotopic Exchange of Carbon Monoxide, Carbon Dioxide, Carbonate, and Formate on TiO2 Journal of Physical Chemistry B. ,vol. 106, pp. 11240- 11245 ,(2002) , 10.1021/JP0211988
J Wei, P Hing, ZQ Mo, None, TEM, XPS and FTIR characterization of sputtered carbon nitride films Surface and Interface Analysis. ,vol. 28, pp. 208- 211 ,(1999) , 10.1002/(SICI)1096-9918(199908)28:1<208::AID-SIA578>3.0.CO;2-8