Catalytic deoxygenation on transition metal carbide catalysts

摘要: We discuss the evolution of catalytic function interstitial transition metal formulations as a result bulk and surface structure modifications via alteration synthesis reaction conditions, specifically, in context deoxygenation reactions. compare contrast techniques molybdenum tungsten carbides, including temperature programmed ultra-high vacuum methods, note that stoichiometric reactions may occur on phase-pure materials situ modification during likely results formation oxycarbides. surmise metal–acid bifunctionality carbides can be tuned oxygen due to inherent oxophilicity these materials, we demonstrate use chemical titration methods assess site requirements formulations.