Photodissociation spectroscopy of the negative ion dimer of toluquinone

作者: Paul B. Comita , John I. Brauman

DOI: 10.1021/JA00259A001

关键词: Radical ionIon cyclotron resonanceIonChemistryBond-dissociation energyPhotochemistryVibronic spectroscopyDimerPhotodissociationMolecular physicsDissociation (chemistry)Colloid and Surface ChemistryBiochemistryGeneral chemistryCatalysis

摘要: The photodissociation spectrum of the negative ion dimer toluquinone has been determined in an cyclotron resonance spectrometer. A charge transition at 1.9 eV, which displays individual vibronic transitions high resolution, identified. bond dissociation energy and electron affinity were from data. was fit to a single-oscillator theoretical model details electronic structure extracted. data indicates that odd radical is strongly localized.

参考文章(0)