State of water in osmotic processes

作者: P.F. Scholander

DOI: 10.1016/0026-2862(71)90027-6

关键词: ImbibitionVapour pressure of waterThermodynamicsMaterials scienceSemipermeable membraneOsmosisForward osmosisPartial pressureOsmotic pressureVapor pressure

摘要: Abstract Osmosis and imbibition depend on solute, or matrix, pressure respectively acting a boundary. If the boundary is semipermeable membrane, due to solute matrix alone; if it free surface, balance of forces gives negative solvent, with consequent lowering vapor pressure. Osmotic flux through dialyzing membrane purely hydraulic, not uniquely determined by water potential; only in diffusional osmosis are these parameters determinants. flux, swelling, caused gradient partial itself. This unified interpretation based upon experimentally verified entities: (1) fluid pressures, (2) independence from solvent at equilibrium, (3) fundamental role for (4) produced drag under nonequilibrium conditions.

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