Recent Advances in Layered Ti 3 C 2 T x MXene for Electrochemical Energy Storage

作者: Dongbin Xiong , Xifei Li , Zhimin Bai , Shigang Lu

DOI: 10.1002/SMLL.201703419

关键词: NitrideAnodeEnergy storageElectrochemistryBand gapMXenesNanotechnologySupercapacitorMaterials scienceBattery (electricity)

摘要: Ti3 C2 Tx , a typical representative among the emerging family of 2D layered transition metal carbides and/or nitrides referred to as MXenes, has exhibited multiple advantages including metallic conductivity, plastic layer structure, small band gaps, and hydrophilic nature its functionalized surface. As result, this material is intensively investigated for application in energy storage field. The composition, morphology texture, surface chemistry, structural configuration directly influence electrochemical performance, e.g., use well-designed rechargeable battery anode significantly enhanced performance by providing more chemically active interfaces, shortened ion-diffusion lengths, improved in-plane carrier/charge-transport kinetics. Some recent progresses MXene are achieved storage. This Review summarizes advances synthesis applications supercapacitors, lithium-ion batteries, sodium-ion lithium-sulfur batteries. current opportunities future challenges addressed energy-storage devices. seeks provide rational in-depth understanding relation between nanostructural/chemical composition which will promote further development MXenes applications.

参考文章(249)
M. R. Lukatskaya, O. Mashtalir, C. E. Ren, Y. Dall'Agnese, P. Rozier, P. L. Taberna, M. Naguib, P. Simon, M. W. Barsoum, Y. Gogotsi, Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide Science. ,vol. 341, pp. 1502- 1505 ,(2013) , 10.1126/SCIENCE.1241488
Xianfen Wang, Satoshi Kajiyama, Hiroki Iinuma, Eiji Hosono, Shinji Oro, Isamu Moriguchi, Masashi Okubo, Atsuo Yamada, Pseudocapacitance of MXene nanosheets for high-power sodium-ion hybrid capacitors Nature Communications. ,vol. 6, pp. 6544- 6544 ,(2015) , 10.1038/NCOMMS7544
Joseph Halim, Maria R. Lukatskaya, Kevin M. Cook, Jun Lu, Cole R. Smith, Lars-Åke Näslund, Steven J. May, Lars Hultman, Yury Gogotsi, Per Eklund, Michel W. Barsoum, Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films Chemistry of Materials. ,vol. 26, pp. 2374- 2381 ,(2014) , 10.1021/CM500641A
A L Ivanovskii, A N Enyashin, Graphene-like transition-metal nanocarbides and nanonitrides Russian Chemical Reviews. ,vol. 82, pp. 735- 746 ,(2013) , 10.1070/RC2013V082N08ABEH004398
Y. Zhu, S. Murali, M. D. Stoller, K. J. Ganesh, W. Cai, P. J. Ferreira, A. Pirkle, R. M. Wallace, K. A. Cychosz, M. Thommes, D. Su, E. A. Stach, R. S. Ruoff, Carbon-based Supercapacitors Produced by Activation of Graphene Science. ,vol. 332, pp. 1537- 1541 ,(2011) , 10.1126/SCIENCE.1200770
P. Simon, Y. Gogotsi, B. Dunn, Where Do Batteries End and Supercapacitors Begin Science. ,vol. 343, pp. 1210- 1211 ,(2014) , 10.1126/SCIENCE.1249625
Yu Xie, Michael Naguib, Vadym N. Mochalin, Michel W. Barsoum, Yury Gogotsi, Xiqian Yu, Kyung-Wan Nam, Xiao-Qing Yang, Alexander I. Kolesnikov, Paul R. C. Kent, Role of Surface Structure on Li-Ion Energy Storage Capacity of Two-Dimensional Transition-Metal Carbides Journal of the American Chemical Society. ,vol. 136, pp. 6385- 6394 ,(2014) , 10.1021/JA501520B
Fanyu Ning, Mingfei Shao, Chenglong Zhang, Simin Xu, Min Wei, Xue Duan, Co3O4@layered double hydroxide core/shell hierarchical nanowire arrays for enhanced supercapacitance performance Nano Energy. ,vol. 7, pp. 134- 142 ,(2014) , 10.1016/J.NANOEN.2014.05.002
Christopher Eames, M. Saiful Islam, Ion Intercalation into Two-Dimensional Transition-Metal Carbides: Global Screening for New High-Capacity Battery Materials Journal of the American Chemical Society. ,vol. 136, pp. 16270- 16276 ,(2014) , 10.1021/JA508154E