Crystallization behavior of sputter-deposited amorphous Ge2Sb2Te5 thin films

作者: Tae H. Jeong , Myong R. Kim , Hun Seo , Sang J. Kim , Sang Y. Kim

DOI: 10.1063/1.370803

关键词: Differential scanning calorimetryMaterials scienceThin filmEllipsometryDiffractionCrystallographyTransmission electron microscopySputteringCrystallizationAnalytical chemistryAmorphous solid

摘要: The crystallization behavior of amorphous Ge2Sb2Te5 thin films were investigated by using differential scanning calorimetry, x-ray diffraction, and optical reflectivity measurements. analysis in situ ellipsometry isotherm based on the Johnson–Mehl–Avrami equation revealed that process near 150 °C was a two-step process. In this alloy film, kinetic exponents about 4.4 for first stage 1.1 second stage. A model cascaded is proposed. proposed showed good agreement with experimental results obtained transmission electron microscopy diffraction.

参考文章(3)
H. E. Kissinger, Reaction Kinetics in Differential Thermal Analysis Analytical Chemistry. ,vol. 29, pp. 1702- 1706 ,(1957) , 10.1021/AC60131A045
J. W. Christian, H. M. Otte, The theory of transformations in metals and alloys ,(1975)
Noboru Yamada, Eiji Ohno, Kenichi Nishiuchi, Nobuo Akahira, Masatoshi Takao, Rapid‐phase transitions of GeTe‐Sb2Te3 pseudobinary amorphous thin films for an optical disk memory Journal of Applied Physics. ,vol. 69, pp. 2849- 2856 ,(1991) , 10.1063/1.348620