Algorithmic Identification of the Reactions Related to the Initial Development of the Time Scale That Characterizes CH4/Air Autoignition
作者： Dimitris M. Manias , Dimitris J. Diamantis , Dimitris A. Goussis
DOI: 10.1061/(ASCE)EY.1943-7897.0000249
关键词: Scale (ratio) 、 Thermodynamics 、 Homogeneous 、 Chemistry 、 Singular perturbation 、 Stoichiometry 、 Autoignition temperature
摘要: AbstractThe reactions responsible for the initial development of time scale that characterizes autoignition a homogeneous stoichiometric CH4/air mixture are identified algorithmically using computational singular perturbation method. The analysis considers wide range temperatures and pressures, located below above explosion limit. major role CH3+O2→CH3O+O (at high temperatures), CH3+O2→CH2O+OH low CH2O+O2→HCO+HO2 intermediate temperatures) is identified. results provide some additional insights regarding significance to initiation process generally considered become active at later times.
sci-hub.se 参考文章(25)
Dimitris A. Goussis, Ulrich Maas, Model Reduction for Combustion Chemistry Springer, Dordrecht. pp. 193- 220 ,(2011) , 10.1007/978-94-007-0412-1_9
F.A. Williams, Lectures on applied mathematics in combustion. Past contributions and future problems in laminar and turbulent combustion Physica D: Nonlinear Phenomena. ,vol. 20, pp. 21- 34 ,(1986) , 10.1016/0167-2789(86)90094-1
Antonio L. SÁnchez, Amable LiñÁn, Forman A. Williams, A WKB analysis of radical growth in the hydrogen-air mixing layer Journal of Engineering Mathematics. ,vol. 31, pp. 119- 130 ,(1997) , 10.1023/A:1004235427312
S.H. Lam, D.A. Goussis, Understanding complex chemical kinetics with computational singular perturbation Symposium (International) on Combustion. ,vol. 22, pp. 931- 941 ,(1989) , 10.1016/S0082-0784(89)80102-X
J. Buckmaster, The contribution of asymptotics to combustion Physica D: Nonlinear Phenomena. ,vol. 20, pp. 91- 108 ,(1986) , 10.1016/0167-2789(86)90098-9
S.B. Dworkin, A.M. Schaffer, B.C. Connelly, M.B. Long, M.D. Smooke, M.A. Puccio, B. McAndrew, J.H. Miller, Measurements and calculations of formaldehyde concentrations in a methane/N2/air, non-premixed flame: Implications for heat release rate Proceedings of the Combustion Institute. ,vol. 32, pp. 1311- 1318 ,(2009) , 10.1016/J.PROCI.2008.05.083
Charles K. Westbrook, Frederick L. Dryer, Chemical kinetic modeling of hydrocarbon combustion Progress in Energy and Combustion Science. ,vol. 10, pp. 1- 57 ,(1984) , 10.1016/0360-1285(84)90118-7
D.A. Goussis, S.H. Lam, A study of homogeneous methanol oxidation kinetics using CSP Symposium (International) on Combustion. ,vol. 24, pp. 113- 120 ,(1992) , 10.1016/S0082-0784(06)80018-4
N. Peters, G. Paczko, R. Seiser, K. Seshadri, Temperature cross-over and non-thermal runaway at two-stage ignition of n-heptane Combustion and Flame. ,vol. 128, pp. 38- 59 ,(2002) , 10.1016/S0010-2180(01)00331-5
Habib N Najm, Phillip H Paul, Charles J Mueller, Peter S Wyckoff, On the Adequacy of Certain Experimental Observables as Measurements of Flame Burning Rate Combustion and Flame. ,vol. 113, pp. 312- 332 ,(1998) , 10.1016/S0010-2180(97)00209-5