A mild and efficient rhenium-catalyzed transfer hydrogenation of terminal olefins using alcoholysis of amine–borane adducts as a reducing system
作者： Hailin Dong , Heinz Berke
DOI: 10.1016/J.JORGANCHEM.2011.01.027
关键词: Catalysis 、 Transfer hydrogenation 、 Rhenium 、 Chemistry 、 Homogeneous catalysis 、 Borane 、 Amine gas treating 、 Medicinal chemistry 、 Organic chemistry 、 Adduct
摘要: Abstract [ReBr 2 (NO)(CH 3 CN)(PTA) ] (PTA = 1, 3, 5-triaza-7-phosphaadamantane) catalyzes the alcoholysis of ammonia–borane and amine–boranes catalytic transfer hydrogenations various terminal olefins. Excellent yields were achieved at 70 °C in isopropanol using t BuOK as a co-catalyst affording TOF values up to 396 h −1 .
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