Near Heterosite Li0.1FePO4 Phase Formation as Atmospheric Aging Product of LiFePO4/C Composite. Electrochemical, Magnetic and EPR Study

作者: Verónica Palomares , Aintzane Goñi , Izaskun Gil de Muro , Luis Lezama , Iratxe de Meatza

DOI: 10.1149/1.3611435

关键词: Phase formationElectron paramagnetic resonanceLifepo4 cComposite numberProduct (mathematics)Analytical chemistryMaterials scienceElectrochemistry

摘要:

参考文章(32)
Richard L. Carlin, A. J. van Duyneveldt, Paramagnetism: The Curie Law Springer, Berlin, Heidelberg. pp. 1- 22 ,(1977) , 10.1007/978-3-642-87392-8_1
In Kyu Lee, In-Bo Shim, Chul Sung Kim, Temperature dependent valence states and magnetic properties of lithium delithiated Li0.59FePO4 Journal of Applied Physics. ,vol. 107, pp. 09A522- ,(2010) , 10.1063/1.3337680
Guoying Chen, Xiangyun Song, Thomas J. Richardson, Metastable Solid-Solution Phases in the LiFePO4 ∕ FePO4 System Journal of The Electrochemical Society. ,vol. 154, ,(2007) , 10.1149/1.2732189
V. Palomares, A. Goñi, I. Gil de Muro, I. de Meatza, M. Bengoechea, I. Cantero, T. Rojo, Influence of Carbon Content on LiFePO4 / C Samples Synthesized by Freeze-Drying Process Journal of The Electrochemical Society. ,vol. 156, ,(2009) , 10.1149/1.3205480
M. Stanley Whittingham, Yanning Song, Samuel Lutta, Peter Y. Zavalij, Natasha A. Chernova, Some transition metal (oxy)phosphates and vanadium oxides for lithium batteries Journal of Materials Chemistry. ,vol. 15, pp. 3362- 3379 ,(2005) , 10.1039/B501961C
B León, C Pérez Vicente, JL Tirado, Ph Biensan, C Tessier, None, Optimized Chemical Stability and Electrochemical Performance of LiFePO4 Composite Materials Obtained by ZnO Coating Journal of The Electrochemical Society. ,vol. 155, ,(2008) , 10.1149/1.2828039
Sang Jun Kwon, Cheol Woo Kim, Woon Tae Jeong, Kyung Sub Lee, Synthesis and electrochemical properties of olivine LiFePO4 as a cathode material prepared by mechanical alloying Journal of Power Sources. ,vol. 137, pp. 93- 99 ,(2004) , 10.1016/J.JPOWSOUR.2004.05.048
A.S Andersson, J.O Thomas, The source of first-cycle capacity loss in LiFePO4 Journal of Power Sources. ,vol. 97, pp. 498- 502 ,(2001) , 10.1016/S0378-7753(01)00633-4
Brian Ellis, Laura K. Perry, Dominic H. Ryan, L. F. Nazar, Small Polaron Hopping in LixFePO4 Solid Solutions: Coupled Lithium-Ion and Electron Mobility Journal of the American Chemical Society. ,vol. 128, pp. 11416- 11422 ,(2006) , 10.1021/JA0614114
H. Huang, S.-C. Yin, L. F. Nazar, Approaching Theoretical Capacity of LiFePO4 at Room Temperature at High Rates Electrochemical and Solid State Letters. ,vol. 4, pp. 170- 172 ,(2001) , 10.1149/1.1396695