Arsenic, barium, strontium and uranium geochemistry and their utility as tracers to characterize groundwaters from the Espadán-Calderona Triassic Domain, Spain.

作者: Elena Giménez-Forcada , Marisol Vega-Alegre

DOI: 10.1016/J.SCITOTENV.2014.12.010

关键词: GeologyStrontiumBariumFaciesMineralogyGroundwater rechargeUraniumSulfateGroundwaterGeochemistryAquifer

摘要: Abstract A set of analytical data from the Espadan–Calderona Triassic Domain aquifers was processed using hierarchical agglomerative cluster analysis (HCA) and principal component (PCA), to achieve a quantitative independent approach investigate characteristics groundwater composition possible differences between flows (Spain). Mineralization in series has led presence several metals metalloids groundwater, including As, Mn, Fe U. These are associated with fresher bicarbonate groundwaters, characterized by lower Sr/Ba ratios. Levels containing sulfate evaporitic salt, which interbedded through series, seem exert strong influence on chemistry calcium facies high Sr concentration The application multivariate statistical techniques interpretation results allows differentiation types occurring identification role number minor or trace elements their ratios that can be treated as hydrogeochemical tracers. With them it correlate different recharge waters tectonic morphology Domain.

参考文章(29)
O. García Menéndez, B. J. Ballesteros Navarro, J. López Gutiérrez, El origen del mercurio presente en el acuífero costero de la Plana de Castellón (este de España) Boletín geológico y minero. ,vol. 121, pp. 279- 298 ,(2010)
Donald Langmuir, Aqueous Environmental Geochemistry ,(1997)
I. Morell, E. Giménez, M.V. Esteller, Application of principal components analysis to the study of salinization on the Castellon Plain (Spain) Science of The Total Environment. ,vol. 177, pp. 161- 171 ,(1996) , 10.1016/0048-9697(95)04893-6
Ioannis A. Katsoyiannis, Hans Werner Althoff, Hartmut Bartel, Martin Jekel, The effect of groundwater composition on uranium(VI) sorption onto bacteriogenic iron oxides. Water Research. ,vol. 40, pp. 3646- 3652 ,(2006) , 10.1016/J.WATRES.2006.06.032
A. Smoliński, B. Walczak, J.W. Einax, Hierarchical clustering extended with visual complements of environmental data set Chemometrics and Intelligent Laboratory Systems. ,vol. 64, pp. 45- 54 ,(2002) , 10.1016/S0169-7439(02)00049-7
Samir Kamel, Lassaad Dassi, Kamel Zouari, Brahim Abidi, Geochemical and isotopic investigation of the aquifer system in the Djerid-Nefzaoua basin, southern Tunisia Environmental Earth Sciences. ,vol. 49, pp. 159- 170 ,(2005) , 10.1007/S00254-005-0076-1