Stille cross-couplings of unactivated secondary alkyl halides using monoorganotin reagents.
作者： David A. Powell , Toshihide Maki , Gregory C. Fu
DOI: 10.1021/JA0436300
关键词: Chemistry 、 Stille reaction 、 Halide 、 Primary (chemistry) 、 Alkyl 、 Organic chemistry 、 Reagent 、 Catalysis
摘要: The first catalyst that achieves Stille cross-couplings of secondary (as well as primary) alkyl halides has been developed. method employs easily handled and inexpensive components (NiCl2 2,2‘-bipyridine) and, through the use monoorganotin reagents, avoids formation toxic difficult-to-remove triorganotin side products.
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