Synthesis and Some Properties of the Complexes of Trithia- and Tetrathia[n](1,1′)ferrocenophanes with Cu(BF4)2. Intramolecular Redox Reaction in the Complexes
作者： Masaru Sato , Sadatoshi Akabori , Motomi Katada , Izumi Motoyama , Hirotoshi Sano
DOI: 10.1246/CL.1987.1847
关键词: Atom 、 Ferrocene 、 Chemistry 、 Intramolecular force 、 Cationic polymerization 、 Cyclophane 、 Stereochemistry 、 Polymer chemistry 、 Molecule 、 Redox 、 General chemistry
摘要: The complexes of 1, 5, 8, 12-tetrathia [12]-, 1, 5, 9, 13-tetrathia [13]-, and 1, 5, 9-trithia [9](1, 1′) ferrocenophanes with Cu (BF4) 2 were synthesized. In these complexes, the ferrocene nucleus was oxidized to a cationic ferricenium state and the Cu atom incorporated in the thiamacrocycle was reduced to a Cu (I) state.
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