The enthalpy of combustion of organometallic compounds measured with a vacuum-jacketed aneroid calorimeter The enthalpy of formation of tin tetraphenyl

作者: G.P. Adams , A.S. Carson , P.G. Laye

DOI: 10.1016/0021-9614(69)90069-X

关键词: CalorimeterPhysical chemistryChemistryEnthalpy of atomizationHeat of combustionStandard enthalpy of reactionTinBond energyCombustionStandard enthalpy of formation

摘要: Abstract Lead tetraphenyl has been burnt in an aneroid rotating combustion calorimeter. The standard enthalpy of was ΔH o = −(3115.6 ± 3.6) kcal th mol −1 , which yielded a formation, f (PbPh 4 c) (123.1 . This value used to extend the self-consistent mean bond energy scheme for organo-metallic compounds Group IV, described previously.

参考文章(13)
Karl-Heinz Birr, Die Bildungswärmen von Tetraphenylsilan, Tetraphenylgerman und Tetraphenylzinn Zeitschrift für anorganische und allgemeine Chemie. ,vol. 315, pp. 175- 180 ,(1962) , 10.1002/ZAAC.19623150306
L. Espada, G. Pilcher, H.A. Skinner, Hot-zone reaction calorimetry II. The enthalpies of formation of lead oxides The Journal of Chemical Thermodynamics. ,vol. 2, pp. 647- 653 ,(1970) , 10.1016/0021-9614(70)90039-X
Henry George Denham, John Oxley Kidson, CCXXXVIII.—The ternary system lead oxide–nitrogen pentoxide–water J. Chem. Soc.. ,vol. 0, pp. 1757- 1762 ,(1931) , 10.1039/JR9310001757
W. D. Good, D. W. Scott, J. L. Lacina, J. P. McCullough, Tetramethyllead: Heat of Formation by Rotating-Bomb Calorimetry The Journal of Physical Chemistry. ,vol. 60, pp. 1090- 1095 ,(1956) , 10.1021/J150577A025
S. Sunner, S. Thorén, Tore Ledaal, Hans M. Seip, The Heat of Oxidation of Aqueous Arsenious Oxide with Gaseous Chlorine. Acta Chemica Scandinavica. ,vol. 18, pp. 1528- 1532 ,(1964) , 10.3891/ACTA.CHEM.SCAND.18-1528
J. A. Kerr, Bond Dissociation Energies by Kinetic Methods Chemical Reviews. ,vol. 66, pp. 465- 500 ,(1966) , 10.1021/CR60243A001