Photoluminescent and Thermoluminescent Studies of Dy3+ and Eu3+ Doped Y2O3 Phosphors.

作者: Tarkeshwari Verma , Sadhana Agrawal

DOI: 10.1007/S10895-018-2208-5

关键词: Fourier transform infrared spectroscopyThermoluminescenceSpectroscopyPhosphorYttriumDopingAnalytical chemistryPhotoluminescenceChemistryInfrared spectroscopy

摘要: Eu3+ doped and Dy3+ codoped yttrium oxide (Y2O3) phosphors have been prepared using solid-state reaction technique (SSR). The were characterized by X-ray diffractometer (XRD), energy dispersive (EDX) spectroscopy, scanning electron microscopy (SEM) Fourier transforms infrared spectroscopy (FTIR) techniques. Photoluminescence (PL) Thermoluminescence (TL) properties studied in detail. PL emission spectra recorded for under excitation wavelength 254 nm, which show a high intense peak at 613 nm Y2O3:Dy3+, (1:1.5 mol %) phosphor. correlated color temperature (CCT) CIE analysis performed the synthesized phosphors. TL glow curves Eu3+doped Dy3+codoped to study heating rate effect dose response. kinetic parameters calculated shape method UV γ exposures through computerized curve deconvolution (CGCD) technique. second order kinetics activation energies varying from 5.823 × 10− 1 18.608 × 10− 1 eV.

参考文章(32)
N.J. Shivaramu, K.R. Nagabhushana, B.N. Lakshminarasappa, Fouran Singh, Ion beam induced luminescence studies of sol gel derived Y2O3:Dy3+ nanophosphors Journal of Luminescence. ,vol. 169, pp. 627- 634 ,(2016) , 10.1016/J.JLUMIN.2015.07.054
S. Som, S. K. Sharma, S. P. Lochab, Morphology, ion impact, and kinetic parameters of swift heavy‐ion‐induced Y2O3:Dy3+ phosphor Physica Status Solidi (a). ,vol. 210, pp. 1624- 1635 ,(2013) , 10.1002/PSSA.201329197
N.J. Shivaramu, B.N. Lakshminarasappa, K.R. Nagabhushana, Fouran Singh, Synthesis characterization and luminescence studies of gamma irradiated nanocrystalline yttrium oxide Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 154, pp. 220- 231 ,(2016) , 10.1016/J.SAA.2015.09.019
Timur Sh. Atabaev, Hong Ha Thi Vu, Hyung-Kook Kim, Yoon-Hwae Hwang, Synthesis and optical properties of Dy3+-doped Y2O3 nanoparticles Journal of the Korean Physical Society. ,vol. 60, pp. 244- 248 ,(2012) , 10.3938/JKPS.60.244
Ravindra P. Singh, Kiran Gupta, Ashutosh Pandey, Anjana Pandey, Synthesis and Characterization of Eu +++ Doped Y 2 O 3 (Red Phosphor) and Tb +++ Doped Y 2 O 3 (Green Phosphor) by Hydrothermal Processes World Journal of Nano Science and Engineering. ,vol. 02, pp. 13- 18 ,(2012) , 10.4236/WJNSE.2012.21003
Bernard Dennis Cullity, Elements of X-ray diffraction ,(1956)
L Robindro Singh, RS Ningthoujam, V Sudarsan, Iti Srivastava, S Dorendrajit Singh, GK Dey, SK Kulshreshtha, None, Luminescence study on Eu(3+) doped Y(2)O(3) nanoparticles: particle size, concentration and core-shell formation effects. Nanotechnology. ,vol. 19, pp. 055201- ,(2008) , 10.1088/0957-4484/19/05/055201
Qingbo Liu, Yufeng Liu, Zhiping Yang, Yue Han, Xu Li, Guangsheng Fu, Multiwavelength excited white-emitting phosphor Dy3+-activated Ba3Bi(PO4)3 Journal of Alloys and Compounds. ,vol. 515, pp. 16- 19 ,(2012) , 10.1016/J.JALLCOM.2011.11.114