Evidence of the relaxor-paraelectric phase transition in Pb(Fe2/3W1/3)O3 ceramics

作者: Liliana Mitoseriu , Maria M. Carnasciali , Paolo Piaggio , Paolo Nanni

DOI: 10.1063/1.1530711

关键词: CurieFerroelectric ceramicsX-ray crystallographyCondensed matter physicsDielectricDiffractionRaman scatteringRaman spectroscopyPhase transitionMaterials sciencePhysics and Astronomy (miscellaneous)

摘要: The transition relaxor-paraelectric in Pb(Fe2/3W1/3)O3 ceramics was studied by x-ray diffraction and Raman scattering at temperatures the range of 85–800 K. For high angles (160° 162°), a slight difference between two phases found. spectra show an evolution with temperature anomalies bands 848 cm−1 147 (shift intensity) Curie temperatures. This behavior is interpreted as experimental evidence perturbations nanopolar ordering related to phase transition.

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