Study in support effect of In2O3/MOx (M = Al, Si, Zr) catalysts for dehydrogenation of propane in the presence of CO2

作者: Miao Chen , Jia-Ling Wu , Yong-Mei Liu , Yong Cao , Li Guo

DOI: 10.1016/J.APCATA.2011.08.018

关键词: PropaneCatalysisChemistryDehydrogenationDispersion (chemistry)Incipient wetness impregnationInorganic chemistryDesorptionPopulationWater-gas shift reaction

摘要: Two series of binary In2O3/MOx (M= Al, Zr, Si) catalysts with low (3wt%) and high (10wt%) In2O3 loadings were prepared via an incipient wetness impregnation method. The support effect has been investigated in detail by testing the propane dehydrogenation (PDH) reaction both in the presence and absence of CO2. Physico-chemical properties including surface composition, redox and acidic/basic properties of the supported In2O3 were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, H2 temperature …

参考文章(24)
R. Grabowski, Kinetics of Oxidative Dehydrogenation of C2‐C3Alkanes on Oxide Catalysts Catalysis Reviews. ,vol. 48, pp. 199- 268 ,(2006) , 10.1080/01614940600631413
G. Aguilar-Ríos, M. Valenzuela, P. Salas, H. Armendáriz, P. Bosch, G. Del Toro, R. Silva, V. Bertín, S. Castillo, A. Ramírez-Solís, I. Schifter, Hydrogen interactions and catalytic properties of platinum-tin supported on zinc aluminate Applied Catalysis A-general. ,vol. 127, pp. 65- 75 ,(1995) , 10.1016/0926-860X(95)00269-3
Yoshihiro Sakurai, Takamasa Suzaki, Na-oki Ikenaga, Toshimitsu Suzuki, Dehydrogenation of ethylbenzene with an activated carbon-supported vanadium catalyst Applied Catalysis A: General. ,vol. 192, pp. 281- 288 ,(2000) , 10.1016/S0926-860X(99)00398-1
Kiyoharu Nakagawa, Chiaki Kajita, Kimito Okumura, Na-oki Ikenaga, Mikka Nishitani-Gamo, Toshihiro Ando, Tetsuhiko Kobayashi, Toshimitsu Suzuki, Role of carbon dioxide in the dehydrogenation of ethane over gallium-loaded catalysts Journal of Catalysis. ,vol. 203, pp. 87- 93 ,(2001) , 10.1006/JCAT.2001.3306
Shaobin Wang, Z. H. Zhu, Catalytic Conversion of Alkanes to Olefins by Carbon Dioxide Oxidative Dehydrogenation-A Review Energy & Fuels. ,vol. 18, pp. 1126- 1139 ,(2004) , 10.1021/EF0340716
Ye Wang, Yoshihiko Ohishi, Tetsuya Shishido, Qinghong Zhang, Wei Yang, Qian Guo, Huilin Wan, Katsuomi Takehira, Characterizations and catalytic properties of Cr-MCM-41 prepared by direct hydrothermal synthesis and template-ion exchange Journal of Catalysis. ,vol. 220, pp. 347- 357 ,(2003) , 10.1016/S0021-9517(03)00278-1
A. Gervasini, J. A. Perdigon-Melon, C. Guimon, A. Auroux, An in-depth study of supported In2O3 catalysts for the selective catalytic reduction of NOx: the influence of the oxide support. Journal of Physical Chemistry B. ,vol. 110, pp. 240- 249 ,(2006) , 10.1021/JP0532824
Bingjun Xu, Bo Zheng, Weiming Hua, Yinghong Yue, Zi Gao, Support effect in dehydrogenation of propane in the presence of CO2 over supported gallium oxide catalysts Journal of Catalysis. ,vol. 239, pp. 470- 477 ,(2006) , 10.1016/J.JCAT.2006.02.017
Piotr Michorczyk, Jan Ogonowski, Dehydrogenation of propane to propene over gallium oxide in the presence of CO2 Applied Catalysis A-general. ,vol. 251, pp. 425- 433 ,(2003) , 10.1016/S0926-860X(03)00368-5