Functional models for catechol 1,2-dioxygenase. The role of the iron(III) center

作者: David D. Cox , Lawrence. Que

DOI: 10.1021/JA00232A021

关键词: Catechol dioxygenaseCatechol 1,2-dioxygenaseCenter (algebra and category theory)KineticsChemistryEnzyme modelStereochemistryEnzymeLewis acids and bases

摘要: … 5.0 and R„ = 5.8) is limited by some disorder present in the 5-ferr-butyl group on the catechol. The Zerr-butyl methyl carbon atoms were found on a difference map and assigned …

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