Investigation on the Fischer−Tropsch Synthesis with Nitrogen-Containing Syngas over CoPtZrO2/Al2O3 Catalyst
作者： Dongyan Xu , Hongmin Duan , Wenzhao Li , Hengyong Xu
DOI: 10.1021/EF0503717
关键词: Chemistry 、 Syngas to gasoline plus 、 Inorganic chemistry 、 Hydrocarbon 、 Fischer–Tropsch process 、 Syngas 、 Partial oxidation 、 Nitrogen 、 Methane 、 Catalysis
摘要: The Fischer−Tropsch synthesis with nitrogen-containing syngas derived from combined air partial oxidation and CO2 reforming of methane has been performed in a fixed-bed reactor. effects key factors including reaction temperature, pressure, nitrogen content the on performance CoPtZrO2/Al2O3 catalyst were mainly investigated. results indicate that containing high is suitable for initial catalytic activity can be achieved under typical operating conditions. decreasing time stream before reaching steady state was observed, which due to blockage pores by heavy hydrocarbons.
acs.org
sci-hub.se 参考文章(22)
E. Iglesia, S.L. Soled, J.E. Baumgartner, S.C. Reyes, Synthesis and catalytic properties of eggshell cobalt catalysts for the Fischer-Tropsch synthesis Journal of Catalysis. ,vol. 153, pp. 108- 122 ,(1995) , 10.1006/JCAT.1995.1113
Mark E. Dry, Practical and theoretical aspects of the catalytic Fischer-Tropsch process Applied Catalysis A-general. ,vol. 138, pp. 319- 344 ,(1996) , 10.1016/0926-860X(95)00306-1
Thomas Riedel, Michael Claeys, Hans Schulz, Georg Schaub, Sang-Sung Nam, Ki-Won Jun, Myoung-Jae Choi, Gurram Kishan, Kyu-Wan Lee, Comparative study of Fischer–Tropsch synthesis with H2/CO and H2/CO2 syngas using Fe- and Co-based catalysts Applied Catalysis A-general. ,vol. 186, pp. 201- 213 ,(1999) , 10.1016/S0926-860X(99)00173-8
Meilin Jia, Wenzhao Li, Hengyong Xu, Shoufu Hou, Qingjie Ge, An integrated air–POM syngas/dimethyl ether process from natural gas Applied Catalysis A-general. ,vol. 233, pp. 7- 12 ,(2002) , 10.1016/S0926-860X(02)00120-5
Dongyan Xu, Wenzhao Li, Qingjie Ge, Hengyong Xu, A novel process for converting coalmine-drained methane gas to syngas over nickel–magnesia solid solution catalysts Fuel Processing Technology. ,vol. 86, pp. 995- 1006 ,(2005) , 10.1016/J.FUPROC.2004.11.014
E.W. Kuipers, I.H. Vinkenburg, H. Oosterbeek, Chain Length Dependence of α-Olefin Readsorption in Fischer-Tropsch Synthesis Journal of Catalysis. ,vol. 152, pp. 137- 146 ,(1995) , 10.1006/JCAT.1995.1068
Dominique Vanhove, Rafeh Bechara, David Balloy, Catalytic properties of Co/Al2O3 system for hydrocarbon synthesis Applied Catalysis A-general. ,vol. 207, pp. 343- 353 ,(2001) , 10.1016/S0926-860X(00)00672-4
Gary Jacobs, Patricia M Patterson, Yongqing Zhang, Tapan Das, Jinlin Li, Burtron H Davis, FISCHER-TROPSCH SYNTHESIS: DEACTIVATION OF NOBLE METAL PROMOTED CO/AL2O3 CATALYSTS Applied Catalysis A-general. ,vol. 233, pp. 215- 226 ,(2002) , 10.1016/S0926-860X(02)00147-3
Gary Jacobs, Karuna Chaudhari, Dennis Sparks, Yongqing Zhang, Buchang Shi, Robert Spicer, Tapan K. Das, Jinlin Li, Burtron H. Davis, Fischer–Tropsch synthesis: supercritical conversion using a Co/Al2O3 catalyst in a fixed bed reactor☆ Fuel. ,vol. 82, pp. 1251- 1260 ,(2003) , 10.1016/S0016-2361(03)00015-2
Anton C Vosloo, Fischer–Tropsch: a futuristic view Fuel Processing Technology. ,vol. 71, pp. 149- 155 ,(2001) , 10.1016/S0378-3820(01)00143-6