Les spectres de masse dans l' analyse 10e communication [1] les transferts d'hygrogène dans des cétones norbornyliques
作者： Aaln F. Thomas , B. Waillhalm
关键词: Mass spectrum 、 Computational chemistry 、 Stereochemistry 、 Norbornane 、 Ring fission 、 Chemistry 、 Carbonyl derivatives 、 Methyl group
摘要: Some simple rules for predicting the transfer of endo hydrogens in mass spectra norbornane carbonyl derivatives are proposed. Transfers from C-6 to C-2 generally occur, but repressed if a methyl group is on C-1. C-5 can less favorable than 1-3 transfers. Endo-2-acetylnorbornanes undergo γ-hydrogen with ring fission.
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