Silylboranes as New Tools in Organic Synthesis

作者: Toshimichi Ohmura , Michinori Suginome

DOI: 10.1246/BCSJ.82.29

关键词: Organic synthesisChemistryOrganic chemistryGeneral chemistry

摘要: New reactivities of silylboranes are described with their applications to organic synthesis. The add unsaturated compounds such as alkynes, alkenes, 1,3-dienes, and allenes ...

参考文章(68)
Todd B. Marder, Nicholas C. Norman, Transition metal catalysed diboration Topics in Catalysis. ,vol. 5, pp. 63- 73 ,(1998) , 10.1023/A:1019145818515
Toshimichi Ohmura, Kohei Masuda, Michinori Suginome, Silylboranes bearing dialkylamino groups on silicon as silylene equivalents: palladium-catalyzed regioselective synthesis of 2,4-disubstituted siloles. Journal of the American Chemical Society. ,vol. 130, pp. 1526- 1527 ,(2008) , 10.1021/JA073896H
Michinori Suginome, Yoshihiko Ito, Regio- and stereoselective synthesis of boryl-substituted allylsilanes via transition metal-catalyzed silaboration Journal of Organometallic Chemistry. ,vol. 680, pp. 43- 50 ,(2003) , 10.1016/S0022-328X(03)00441-8
Michinori Suginome, Takanori Matsuda, Yoshihiko Ito, Palladium- and Platinum-Catalyzed Silaboration of Methylenecyclopropanes through Selective Proximal or Distal C−C Bond Cleavage Journal of the American Chemical Society. ,vol. 122, pp. 11015- 11016 ,(2000) , 10.1021/JA002885K
Irina Beletskaya, Christina Moberg, Element-element additions to unsaturated carbon-carbon bonds catalyzed by transition metal complexes. Chemical Reviews. ,vol. 106, pp. 2320- 2354 ,(2006) , 10.1021/CR050530J
Yoko Abe, Kei Kuramoto, Masahiro Ehara, Hiroshi Nakatsuji, Michinori Suginome, Masahiro Murakami, Yoshihiko Ito, A mechanism for the palladium-catalyzed regioselective silaboration of allene: A theoretical study Organometallics. ,vol. 27, pp. 1736- 1742 ,(2008) , 10.1021/OM070110F