Reduced graphene oxide paper by supercritical ethanol treatment and its electrochemical properties

作者: Siyang Liu , Ke Chen , You Fu , Suyang Yu , Zhihao Bao

DOI: 10.1016/J.APSUSC.2012.02.023

关键词: Materials scienceGraphene oxide paperAnodeInorganic chemistryCarbon nanotubeLithium batteryLithiumGrapheneSupercritical fluidFourier transform infrared spectroscopy

摘要: Abstract Graphene oxide (GO) paper was treated in supercritical ethanol as a green route for its reduction, which confirmed by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron (XPS), thermogravimetric analysis and conductivity measurements. The reduced GO showed good electrochemical properties. As sole component of the anode lithium ion batteries, specific capacity comparable to those free standing papers hydrazine or carbon nanotube paper. can be potential candidate binder-free high performance batteries.

参考文章(30)
C. Hontoria-Lucas, A.J. López-Peinado, J.de D. López-González, M.L. Rojas-Cervantes, R.M. Martín-Aranda, Study of oxygen-containing groups in a series of graphite oxides: Physical and chemical characterization Carbon. ,vol. 33, pp. 1585- 1592 ,(1995) , 10.1016/0008-6223(95)00120-3
C. Nethravathi, T. Nisha, N. Ravishankar, C. Shivakumara, M. Rajamathi, Graphene–nanocrystalline metal sulphide composites produced by a one-pot reaction starting from graphite oxide Carbon. ,vol. 47, pp. 2054- 2059 ,(2009) , 10.1016/J.CARBON.2009.03.055
Jaemyung Kim, Laura J. Cote, Franklin Kim, Wa Yuan, Kenneth R. Shull, Jiaxing Huang, Graphene Oxide Sheets at Interfaces Journal of the American Chemical Society. ,vol. 132, pp. 8180- 8186 ,(2010) , 10.1021/JA102777P
Chengzhou Zhu, Shaojun Guo, Ping Wang, Li Xing, Youxing Fang, Yueming Zhai, Shaojun Dong, One-pot, water-phase approach to high-quality graphene/TiO2 composite nanosheets Chemical Communications. ,vol. 46, pp. 7148- 7150 ,(2010) , 10.1039/C0CC01459A
Ayato Nagashima, Kenji Nuka, Hiroshi Itoh, Takeo Ichinokawa, Chuhei Oshima, Shigeki Otani, Electronic states of monolayer graphite formed on TiC(111) surface Surface Science. ,vol. 291, pp. 93- 98 ,(1993) , 10.1016/0039-6028(93)91480-D
Caiyun Wang, Dan Li, Chee O. Too, Gordon G. Wallace, Electrochemical Properties of Graphene Paper Electrodes Used in Lithium Batteries Chemistry of Materials. ,vol. 21, pp. 2604- 2606 ,(2009) , 10.1021/CM900764N
Guoxiu Wang, Juan Yang, Jinsoo Park, Xinglong Gou, Bei Wang, Hao Liu, Jane Yao, FACILE SYNTHESIS AND CHARACTERIZATION OF GRAPHENE NANOSHEETS Journal of Physical Chemistry C. ,vol. 112, pp. 8192- 8195 ,(2008) , 10.1021/JP710931H
Tamás Szabó, Ottó Berkesi, Péter Forgó, Katalin Josepovits, Yiannis Sanakis, Dimitris Petridis, Imre Dékány, Evolution of surface functional groups in a series of progressively oxidized graphite oxides Chemistry of Materials. ,vol. 18, pp. 2740- 2749 ,(2006) , 10.1021/CM060258+
C. Lee, X. Wei, J. W. Kysar, J. Hone, Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene Science. ,vol. 321, pp. 385- 388 ,(2008) , 10.1126/SCIENCE.1157996