Thermally Responsive Amphiphilic Conetworks and Gels Based on Poly(N-isopropylacrylamide) and Polyisobutylene
作者： Gergely Kali , Szilvia Vavra , Krisztina László , Béla Iván
DOI: 10.1021/MA400535R
关键词: Copolymer 、 Swelling 、 Poly(N-isopropylacrylamide) 、 Aqueous solution 、 Tetrahydrofuran 、 Amphiphile 、 Polymer chemistry 、 Self-healing hydrogels 、 Glass transition 、 Chemistry
摘要: Novel amphiphilic conetworks (APCN) consisting of thermoresponsive poly(N-isoproplyacrylamide) (PNiPAAm) cross-linked by hydrophobic methacrylate-telechelic polyisobutylene (MA-PIB-MA) were successfully synthesized in a broad composition range. The resulting PNiPAAm-l-PIB (“l” stands for “linked by”) obtained radical copolymerization NiPAAm with MA-PIB-MA tetrahydrofuran, cosolvent all the components. Low amounts extractables substantiated efficient network formation. dependent two glass transition temperatures (Tg) DSC analysis indicate microphase separation components without mixed phases. It was found that are uniformly swellable both water and n-hexane; i.e., these new materials behave either as hydrogels or gels aqueous nonpolar media, respectively. uniform swelling polar solutes indicates cocontinuous (bicontinuous) phase morphology. equilibrium s...
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sci-hub.se 参考文章(88)
Joseph Paul Kennedy, Béla Iván, Designed polymers by carbocationic macromolecular engineering : theory and practice Hanser , Distributed in the USA and Canada by Oxford University Presss. ,(1992)
Guo You Huang, Li Hong Zhou, Qian Cheng Zhang, Yong Mei Chen, Wei Sun, Feng Xu, Tian Jian Lu, Microfluidic hydrogels for tissue engineering Biofabrication. ,vol. 3, pp. 012001- ,(2011) , 10.1088/1758-5082/3/1/012001
Márton Haraszti, Edina Tóth, Béla Iván, Poly(methacrylic acid)-l-Polyisobutylene: A Novel Polyelectrolyte Amphiphilic Conetwork Chemistry of Materials. ,vol. 18, pp. 4952- 4958 ,(2006) , 10.1021/CM061119V
Howard G. Schild, David A. Tirrell, Microcalorimetric detection of lower critical solution temperatures in aqueous polymer solutions The Journal of Physical Chemistry. ,vol. 94, pp. 4352- 4356 ,(1990) , 10.1021/J100373A088
Jonas Scherble, Ralf Thomann, Béla, Rolf Mülhaupt, Formation of CdS nanoclusters in phase‐separated poly(2‐hydroxyethyl methacrylate)‐l‐polyisobutylene amphiphilic conetworks Journal of Polymer Science Part B. ,vol. 39, pp. 1429- 1436 ,(2001) , 10.1002/POLB.1114
M. Heskins, J. E. Guillet, Solution Properties of Poly(N-isopropylacrylamide) Journal of Macromolecular Science, Part A. ,vol. 2, pp. 1441- 1455 ,(1968) , 10.1080/10601326808051910
Claire Mangeney, Fabien Ferrage, Isabelle Aujard, Valérie Marchi-Artzner, Ludovic Jullien, Olivier Ouari, El Djouhar Rékaï, André Laschewsky, Inger Vikholm, Janusz W. Sadowski, Synthesis and properties of water-soluble gold colloids covalently derivatized with neutral polymer monolayers. Journal of the American Chemical Society. ,vol. 124, pp. 5811- 5821 ,(2002) , 10.1021/JA010796H
Irada S. Isayeva, Alan N. Gent, Joseph P. Kennedy, Synthesis and burst strength of water‐swollen immunoisolatory tubules Journal of Polymer Science Part A. ,vol. 40, pp. 2075- 2084 ,(2002) , 10.1002/POLA.10303
S. Rimmer, M.J. German, J. Maughan, Y. Sun, N. Fullwood, J. Ebdon, S. MacNeil, Synthesis and properties of amphiphilic networks 3: preparation and characterization of block conetworks of poly(butyl methacrylate-block-(2,3 propandiol-1-methacrylate-stat-ethandiol dimethacrylate)) Biomaterials. ,vol. 26, pp. 2219- 2230 ,(2005) , 10.1016/J.BIOMATERIALS.2004.07.013
Jinming Hu, Lu Dai, Shiyong Liu, Analyte-Reactive Amphiphilic Thermoresponsive Diblock Copolymer Micelles-Based Multifunctional Ratiometric Fluorescent Chemosensors Macromolecules. ,vol. 44, pp. 4699- 4710 ,(2011) , 10.1021/MA2001146