Dielectric spectra of some common solvents in the microwave region. Dipolar aprotic solvents and amides

作者: J. Barthel , K. Bachhuber , R. Buchner , J.B. Gill , M. Kleebauer

DOI: 10.1016/0009-2614(90)85071-J

关键词: Dispersion (chemistry)PermittivityFormamidePhysical chemistryDielectricPropylene carbonateOrganic chemistryMicrowaveAcetonitrileChemistryRelaxation (NMR)

摘要: Abstract Precise complex permittivity spectra of the amides formamide, N-methylformamide, N,N-dimethylformamide, and N,N-dimethylacetamide dipolar aprotic solvents acetonitrile, propylene carbonate, dimethylsulfoxide were determined in frequency range 0.95-89 GHz. The dielectric relaxation all liquids is non-exponential, ranging from a small symmetrical time distribution for acetonitrile to three discrete dispersion steps NMF.

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