1 H NMR Chemosensing of Potassium Ions Enabled by Guest‐Induced Selectivity Switch of a Gold Nanoparticle/Crown Ether Nanoreceptor
作者： Xiaohuan Sun , Daniele Rosa‐Gastaldo , Federico De Biasi , Federico Rastrelli , Fabrizio Mancin
关键词: Crown ether 、 Potassium 、 Colloidal gold 、 Proton NMR 、 Nuclear magnetic resonance spectroscopy 、 Molecular recognition 、 Polymer chemistry 、 Chemistry 、 Nanoparticle 、 Organic anion
摘要: Invited for this month's cover is the group of Prof. Fabrizio Mancin from University Padova, Italy. The picture shows an 18-crown-6-functionalized gold nanoparticle that switches its molecular recognition preference organic cations to anions in presence potassium ions, thus allowing 1 H NMR sensing potassium. Read full text article at 10.1002/cplu.201900028.
sci-hub.se 参考文章(35)
G.W. Gokel, Cation Binding by Crown Ethers Reference Module in Chemistry, Molecular Sciences and Chemical Engineering#R##N#Comprehensive Supramolecular Chemistry II. ,vol. 1, pp. 203- 216 ,(2017) , 10.1016/B978-0-12-409547-2.05615-8
Yanchuan Zhao, Lily Chen, Timothy M. Swager, Simultaneous Identification of Neutral and Anionic Species in Complex Mixtures without Separation Angewandte Chemie. ,vol. 55, pp. 917- 921 ,(2016) , 10.1002/ANIE.201508085
Aidi Chen, Michael J. Shapiro, NOE Pumping. 2. A High-Throughput Method To Determine Compounds with Binding Affinity to Macromolecules by NMR Journal of the American Chemical Society. ,vol. 122, pp. 414- 415 ,(2000) , 10.1021/JA992588J
Kun Chen, Qinghai Shu, Michael Schmittel, Design strategies for lab-on-a-molecule probes and orthogonal sensing. Chemical Society Reviews. ,vol. 44, pp. 136- 160 ,(2015) , 10.1039/C4CS00263F
Ranganathan Velu, Vayalakkavoor T. Ramakrishnan, Perumal Ramamurthy, Colorimetric and fluorometric chemosensors for selective signaling toward Ca2+ and Mg2+ by aza-crown ether acridinedione-functionalized gold nanoparticles Tetrahedron Letters. ,vol. 51, pp. 4331- 4335 ,(2010) , 10.1016/J.TETLET.2010.06.041
Gaurang Patel, Anish Kumar, Usha Pal, Shobhana Menon, None, Potassium ion recognition by facile dithiocarbamate assembly of benzo-15-crown-5-gold nanoparticles. Chemical Communications. pp. 1849- 1851 ,(2009) , 10.1039/B822734A
Takashi Sakamoto, Hikaru Hayakawa, Kenzo Fujimoto, Development of a Potassium Ion Sensor for 19F Magnetic Resonance Chemical Shift Imaging Based on Fluorine-labeled Thrombin Aptamer Chemistry Letters. ,vol. 40, pp. 720- 721 ,(2011) , 10.1246/CL.2011.720
William S. Price, Spin dynamics: Basics of nuclear magnetic resonance, 2nd edition. Concepts in Magnetic Resonance Part A. ,vol. 34A, pp. 60- 61 ,(2009) , 10.1002/CMR.A.20130
Lei You, Daijun Zha, Eric V. Anslyn, Recent Advances in Supramolecular Analytical Chemistry Using Optical Sensing. Chemical Reviews. ,vol. 115, pp. 7840- 7892 ,(2015) , 10.1021/CR5005524