Infrared spectroscopic studies on metal carbonyl compounds-III: Assignment of the totally symmetric C-O stretching bands of the metal carbonyls, with special respect to the spectra of tetracobalt-dodekacarbonyl and dicobalt-octacarbonyl
作者： G. Bor
DOI: 10.1016/0371-1951(63)80041-7
关键词: Cobalt carbonyl 、 Infrared 、 Bonding problems 、 Physical chemistry 、 Chemistry 、 Dicobalt octacarbonyl 、 Photochemistry 、 Spectral line 、 Metal carbonyl
摘要: Abstract The spectra of several metal carbonyl compounds suggest that the frequency totally symmetric C-O stretching vibration is highest all frequencies a given compound. This result can be justified theoretically. On this basis Co 4 (CO) 12 and 2 8 were re-examined new assignments have been made. In case existence two different structural forms in solution suggested. bonding problems some cobalt are discussed on their v 1 co values.
harvard.edu
elsevier.com
sci-hub.se 参考文章(38)
F Albert Cotton, Andrew Liehr, Geoffrey Wilkinson, None, Spectra and structures of metal-carbon monoxide compounds—II: Manganese and rhenium decacarbonyls☆ Journal of Inorganic and Nuclear Chemistry. ,vol. 2, pp. 141- 148 ,(1956) , 10.1016/0022-1902(56)80059-6
György Bor, László Markó, Bernadett Markó, Kobaltcarbonylderivate des Tetrachlorkohlenstoffs und organischer 1.1.1‐Trihalogenverbindungen: Trikobalt‐enneacarbonyl‐kohlenstoff‐Verbindungen Chemische Berichte. ,vol. 95, pp. 333- 340 ,(1962) , 10.1002/CBER.19620950207
Andrew D. Liehr, On the Use of Local Symmetry in Analyzing the Infrared Spectra of Complex Molecules The Journal of Chemical Physics. ,vol. 24, pp. 162- 163 ,(1956) , 10.1063/1.1700823
Wolfgang Beck, Walter Hieber, Hubert Tengler, Über Pentacarbonylmangan- und -rheniumverbindungen: Dipolmomente und CO-Valenzschwingungsfrequenzen Chemische Berichte. ,vol. 94, pp. 862- 872 ,(1961) , 10.1002/CBER.19610940402
D.F. Keeley, R.E. Johnson, Isotopic exchange reactions of the metal carbonyls Journal of Inorganic and Nuclear Chemistry. ,vol. 11, pp. 33- 41 ,(1959) , 10.1016/0022-1902(59)80212-8
G. Bor, High-resolution infra-red spectrum of the [Fe(CN)5NO]2− ion Journal of Inorganic and Nuclear Chemistry. ,vol. 17, pp. 174- 175 ,(1961) , 10.1016/0022-1902(61)80204-2
Otto Vohler, IR-Absorptionsmessungen an Kobaltcarbonyl-Phosphin-Verbindungen Chemische Berichte. ,vol. 91, pp. 1235- 1238 ,(1958) , 10.1002/CBER.19580910619
H. Stammreich, Oswaldo Sala, Yara Tavares, Raman Spectrum and Structure of Iron Pentacarbonyl The Journal of Chemical Physics. ,vol. 30, pp. 856- 857 ,(1959) , 10.1063/1.1730068
Otto Vohler, IR-Absorptionsmessungen an verschiedenartigen Kobaltcarbonyl-Verbindungen Chemische Berichte. ,vol. 91, pp. 1161- 1164 ,(1958) , 10.1002/CBER.19580910606
Paolo Corradini, Structure of Tetracobaltdodecarbonyl The Journal of Chemical Physics. ,vol. 31, pp. 1676- 1677 ,(1959) , 10.1063/1.1730674