Single-Calcination Synthesis of Pyrochlore-Free 0.9Pb(Mg1/3Nb2/3)O3-0.1PbTiO3and Pb(Mg1/3Nb2/3)O3Ceramics Using a Coating Method
作者： Huiming Gu , Wan Y. Shih , Wei-Heng Shih
DOI: 10.1111/J.1151-2916.2003.TB00002.X
关键词: Pyrochlore 、 Columbite 、 Perovskite (structure) 、 Nuclear chemistry 、 Microstructure 、 Calcination 、 Electroceramics 、 Materials science 、 Mineralogy 、 Aqueous solution 、 Coating 、 Materials Chemistry 、 Ceramics and Composites
摘要: A coating approach for synthesizing 0.9Pb(Mg 1/3 Nb 2/3 )O 3 -0.1PbTiO (0.9PMN-0.1PT) and PMN using a single calcination step was demonstrated. The pyrochlore phase prevented by Mg(OH) 2 on O 5 particles. Coating of done precipitating in an aqueous suspension at pH 10. confirmed optical micrographs zeta-potential measurements. treatment the -coated particles mixed with appropriate amounts PbO PbTiO powders 900°C h produced pyrochlore-free perovskite 0.9PMN-0.1PT powders. elimination attributed to separation coating. improved mixing decreased temperature complete columbite conversion ∼850°C. were sintered 97% density 1150°C. ceramics exhibited dielectric constant maximum ∼24 660 45°C frequency 1 kHz.
sci-hub.se 参考文章(11)
M. Lejeune, J.P. Boilot, Formation mechanism and ceramic process of the ferroelectric perovskites: Pb (Mg13Nb23)O3 and Pb (Fe12Nb12)O3 Ceramics International. ,vol. 8, pp. 99- 103 ,(1982) , 10.1016/0272-8842(82)90025-6
Kyoung R. Han, Sojin Kim, Hee Jin Koo, New Preparation Method of Low‐Temperature‐Sinterable Perovskite 0.9Pb(Mg1/3Nb2/3)O3‐0.1PbTiO3 Powder and Its Dielectric Properties Journal of the American Ceramic Society. ,vol. 81, pp. 2998- 3000 ,(2005) , 10.1111/J.1151-2916.1998.TB02725.X
Jong-Gab Baek, Tetsuhiko Isobe, Mamoru Senna, Synthesis of Pyrochlore‐Free 0.9Pb(Mg1/3Nb2/3)O3‐0.1PbTiO3 Ceramics via a Soft Mechanochemical Route Journal of the American Ceramic Society. ,vol. 80, pp. 973- 981 ,(2005) , 10.1111/J.1151-2916.1997.TB02929.X
K. Katayama, M. Abe, T. Akiba, H. Yanagida, Sintering and dielectric properties of single-phase Pb(Mg13Nb23)O3-PbTiO3 Journal of The European Ceramic Society. ,vol. 5, pp. 183- 191 ,(1989) , 10.1016/0955-2219(89)90034-4
Yeshwanth Narendar, Gary L. Messing, Kinetic Analysis of Combustion Synthesis of Lead Magnesium Niobate from Metal Carboxylate Gels Journal of the American Ceramic Society. ,vol. 80, pp. 915- 924 ,(2005) , 10.1111/J.1151-2916.1997.TB02922.X
S.L. Swartz, T.R. Shrout, Fabrication of perovskite lead magnesium niobate Materials Research Bulletin. ,vol. 17, pp. 1245- 1250 ,(1982) , 10.1016/0025-5408(82)90159-3
L. Eric Cross, Relaxorferroelectrics: An overview Ferroelectrics. ,vol. 151, pp. 305- 320 ,(1994) , 10.1080/00150199408244755
Frederic Chaput, Jean-Pierre Boilo, Martine Lejeune, Renee Papiernik, Liliane G. Hubert-Pfalzgraf, Low‐Temperature Route to Lead Magnesium Niobate Journal of the American Ceramic Society. ,vol. 72, pp. 1355- 1357 ,(1989) , 10.1111/J.1151-2916.1989.TB07651.X
Palaniappan Ravindranathan, Sridhar Komarneni, Amar S. Bhalla, Rustum Roy, Synthesis and Dielectric Properties of Solution Sol‐Gel‐Derived 0.9Pb(Mg1/3Nb2/3)O3–0.1PbTiO3 Ceramics Journal of the American Ceramic Society. ,vol. 74, pp. 2996- 2999 ,(1991) , 10.1111/J.1151-2916.1991.TB04292.X
강상구, 김환, 이종국, 이종필, 용매 증발법에 의한 Pd(Mg 1/3 Nb 2/3 )O₃ 분말 합성 및 유전 성질 Journal of The Korean Ceramic Society. ,vol. 33, pp. 17- 24 ,(1996)