Nylon 6 nanocomposites prepared by a melt mixing masterbatch process

作者: Rhutesh K. Shah , D.R. Paul

DOI: 10.1016/J.POLYMER.2004.02.058

关键词: Composite materialNanocompositeExfoliation jointRheometryMasterbatchNylon 6OrganoclayMontmorilloniteMaterials scienceMolding (process)

摘要: Abstract A melt mixing masterbatch process for preparing nylon 6 nanocomposites that provides good exfoliation and low viscosities has been investigated. It is known high molecular weight (HMW) grades of lead to higher levels organoclays than do (LMW) 6. However, LMW have lower viscosities, which are favorable certain commercial applications like injection molding. To resolve this, a two-step prepare based on explored here. In the first step, organoclay in HMW prepared by processing give exfoliation. second diluted with desired montmorillonite (MMT) content reduce viscosity. Wide angle X-ray scattering, transmission electron microscopy, stress–strain analysis were used evaluate effect clay morphology physical properties final nanocomposite. The viscosity was characterized Brabender Torque Rheometry. approach lie between those corresponding composites directly from clear trade-off observed modulus processability. Masterbatches MMT offer significant decrease small reduction compared Higher concentrations less trade-off.

参考文章(20)
G. W. Beall, Thomas J. Pinnavaia, Polymer-clay nanocomposites John Wiley. ,(2000)
Timothy Dean Fornes, Polyamide-layered silicate nanocomposites by melt processing Ph.D. Thesis. ,(2003)
T.D. Fornes, P.J. Yoon, H. Keskkula, D.R. Paul, Nylon 6 nanocomposites: the effect of matrix molecular weight Polymer. ,vol. 42, pp. 9929- 9940 ,(2001) , 10.1016/S0032-3861(01)00552-3
T.D Fornes, P.J Yoon, D.L Hunter, H Keskkula, D.R Paul, Effect of organoclay structure on nylon 6 nanocomposite morphology and properties Polymer. ,vol. 43, pp. 5915- 5933 ,(2002) , 10.1016/S0032-3861(02)00400-7
Arimitsu Usuki, Yoshitsugu Kojima, Masaya Kawasumi, Akane Okada, Yoshiaki Fukushima, Toshio Kurauchi, Osami Kamigaito, Synthesis of nylon 6-clay hybrid Journal of Materials Research. ,vol. 8, pp. 1179- 1184 ,(1993) , 10.1557/JMR.1993.1179
J.W Cho, D.R Paul, Nylon 6 nanocomposites by melt compounding Polymer. ,vol. 42, pp. 1083- 1094 ,(2001) , 10.1016/S0032-3861(00)00380-3
P.J. Yoon, T.D. Fornes, D.R. Paul, Thermal expansion behavior of nylon 6 nanocomposites Polymer. ,vol. 43, pp. 6727- 6741 ,(2002) , 10.1016/S0032-3861(02)00638-9
Wei Xie, Zongming Gao, Wei-Ping Pan, Doug Hunter, Anant Singh, Richard Vaia, Thermal Degradation Chemistry of Alkyl Quaternary Ammonium Montmorillonite Chemistry of Materials. ,vol. 13, pp. 2979- 2990 ,(2001) , 10.1021/CM010305S
A.J. Oshinski, H. Keskkula, D.R. Paul, The role of matrix molecular weight in rubber toughened nylon 6 blends: 1. Morphology Polymer. ,vol. 37, pp. 4891- 4907 ,(1996) , 10.1016/0032-3861(96)00373-4