Coriolis interactions and infrared intensities in fluoroform
作者： Shigeo Kondo , Shinnosuke Saëki
DOI: 10.1063/1.441106
关键词: Atomic physics 、 Perturbation (astronomy) 、 Dipole 、 Infrared 、 Molecule 、 Chemistry 、 Fluoroform 、 Halogen 、 Nuclear magnetic resonance 、 Ab initio 、 CNDO/2
摘要: Infrared intensities of the fundamental bands CHF3 molecule were remeasured. The Coriolis interaction between ν3 and ν5 as well that ν6 was analyzed to determine sign perturbation. As a result, relative signs all (∂p/∂Qi)’s in this have been determined without using CNDO/2 method or an ab initio calculation. An empirical rule on CF bond intensity parameters is proposed by name ’’CF‐bond criteria’’, according which negative dipole moment enhanced direction displacements F atoms both stretching deformation modes. Further, possibility suggested extend halogen atoms.
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