An orbital phase theory.
作者： Satoshi Inagaki
DOI: 10.1007/128_2008_40
关键词: Chemical physics 、 Atomic orbital 、 Non-bonding orbital 、 Phase (matter) 、 Electron 、 Organic reaction 、 Tautomer 、 Reactivity (chemistry) 、 Chemistry 、 Molecule
摘要: Cyclic orbital interactions are contained in non-cyclic conjugation as well cyclic conjugation. For effective interactions, the orbitals required to meet simultaneously phase continuity conditions: (1) out of relation between electron-donating orbitals; (2) electron-accepting and -accepting orbitals. The theory is applicable diverse chemical phenomena conjugate systems, e.g., relative stabilities isomers, selectivities reactions through transition structures. also includes rules for i.e., Wooward–Hoffmann rule stereoselection organic Hueckel 4n + 2π electron aromatic molecules. Derivation applications reviewed.
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