作者： R. Weiss , J. Fischer , A. De Cian , M. Lachkar , D. Chabach
DOI:
关键词: Porphyrin 、 Chemistry 、 Metal 、 X-ray crystallography 、 Molecule 、 Lanthanide 、 Steric effects 、 Proton nmr spectroscopy 、 Phthalocyanine 、 Crystallography
摘要: Two new dicerium(III) mixed-ligand complexes, in which the two metal cations are coordinated to eight nitrogen atoms of a porphyrin and phthalocyanine, have been isolated characterized by UV-visible proton NMR spectroscopy X-ray crystallography at -100°C. Their centrosymmetric molecular structures sandwich triple-decker type.