On the thermal treatment of plastic mixtures of MSW: Pyrolysis kinetics
作者： Chao-Hsiung Wu , Ching-Yuan Chang , Jwo-Luen Hor , Shin-Min Shih , Leo-Wang Chen
DOI: 10.1016/0956-053X(93)90046-Y
关键词: High-density polyethylene 、 Pyrolysis 、 Low-density polyethylene 、 Waste management 、 Polyvinyl chloride 、 Polypropylene 、 Thermogravimetric analysis 、 Materials science 、 Chemical engineering 、 Char 、 Polyethylene
摘要: Abstract The pyrolysis kinetics of six principal plastic materials municipal solid waste (MSW) and their mixtures were investigated by a thermal gravimetric analysis (TGA) reaction system at various heating rates 1, 2, 5.5 K/min in nitrogen atmosphere. results indicated that the high-density polyethylene (HDPE), low-density (LDPE), polypropylene (PP), polystyrene (PS), acrylonitrile-butadiene-styrene (ABS) copolymer can be considered as one stage described an overall rate equation. history polyvinyl chloride (PVC) experimental conditions this investigation consisted two distinct stages with four reactions, which also expressed interaction between components mixture was insignificant. for slow represented combining corresponding MSW together prediction char yield. satisfactorily fitted proposed chemical equations.
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