Self‐Assembly of Amphiphilic Calix[4]arenes in Aqueous Solution

作者: M. Strobel , K. Kita-Tokarczyk , A. Taubert , C. Vebert , P. A. Heiney

DOI: 10.1002/ADFM.200500212

关键词: Organic chemistryLyotropicAlkylChemistryPolymer chemistryCalixareneLyotropic liquid crystalAqueous solutionCarboxylic acidMonolayerAmphiphile

摘要: The self-assembly of amphiphilic calix[4]arenes with either a carboxylic acid or trimethyl ammonium head group and different alkyl chains in aqueous solution was investigated. carboxylated calixarene forms vesicles dilute stable monolayers on water. In contrast, the provides high water solubility no observed aggregation. At concentrations, all amphiphiles form lyotropic liquid crystals.

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